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Structural distortions in M[E(SiMe₃)₂]₃ complexes (M = group 15, f-element; E = N, CH): is three a crowd?.

Inorganic chemistry

Boyde NC, Chmely SC, Hanusa TP, Rheingold AL, Brennessel WW.
PMID: 25171144
Inorg Chem. 2014 Sep 15;53(18):9703-14. doi: 10.1021/ic501232z. Epub 2014 Aug 29.

The tris(bistrimethylsilylamido) species P[N(SiMe3)2]3 (1) and As[N(SiMe3)2]3 (2) have been prepared through halide metathesis in high yield. Their single crystal X-ray structures, along with that of Sb[N(SiMe3)2]3 (3), complete the series of structurally authenticated group 15 M[N(SiMe3)2]3 complexes (the...

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Boyde NC, Chmely SC, Hanusa TP, et al. Structural distortions in M[E(SiMe₃)₂]₃ complexes (M = group 15, f-element; E = N, CH): is three a crowd?. Inorg Chem. 2014;53(18):9703-14doi: 10.1021/ic501232z.
Boyde, N. C., Chmely, S. C., Hanusa, T. P., Rheingold, A. L., & Brennessel, W. W. (2014). Structural distortions in M[E(SiMe₃)₂]₃ complexes (M = group 15, f-element; E = N, CH): is three a crowd?. Inorganic chemistry, 53(18), 9703-14. https://doi.org/10.1021/ic501232z
Boyde, Nicholas C, et al. "Structural distortions in M[E(SiMe₃)₂]₃ complexes (M = group 15, f-element; E = N, CH): is three a crowd?." Inorganic chemistry vol. 53,18 (2014): 9703-14. doi: https://doi.org/10.1021/ic501232z
Boyde NC, Chmely SC, Hanusa TP, Rheingold AL, Brennessel WW. Structural distortions in M[E(SiMe₃)₂]₃ complexes (M = group 15, f-element; E = N, CH): is three a crowd?. Inorg Chem. 2014 Sep 15;53(18):9703-14. doi: 10.1021/ic501232z. Epub 2014 Aug 29. PMID: 25171144.
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Experimental and computational study of a new wheel-shaped {[W5O21]3[(U(VI)O))2(μ-O2)]3}30- polyoxometalate.

Inorganic chemistry

Miró P, Ling J, Qiu J, Burns PC, Gagliardi L, Cramer CJ.
PMID: 22857707
Inorg Chem. 2012 Aug 20;51(16):8784-90. doi: 10.1021/ic3005536. Epub 2012 Aug 02.

A new wheel-shaped polyoxometalate {[W(5)O(21)](3)[(U(VI)O(2))(2)(μ-O(2))](3)}(30-) has been synthesized and structurally characterized. The calculated electrostatic potential reveals the protonation of several μ-oxo bridges reducing the polyoxometalate total charge. A protonated structure computed at the density functional level of theory (DFT)...

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Miró P, Ling J, Qiu J, et al. Experimental and computational study of a new wheel-shaped {[W5O21]3[(U(VI)O))2(μ-O2)]3}30- polyoxometalate. Inorg Chem. 2012;51(16):8784-90doi: 10.1021/ic3005536.
Miró, P., Ling, J., Qiu, J., Burns, P. C., Gagliardi, L., & Cramer, C. J. (2012). Experimental and computational study of a new wheel-shaped {[W5O21]3[(U(VI)O))2(μ-O2)]3}30- polyoxometalate. Inorganic chemistry, 51(16), 8784-90. https://doi.org/10.1021/ic3005536
Miró, Pere, et al. "Experimental and computational study of a new wheel-shaped {[W5O21]3[(U(VI)O))2(μ-O2)]3}30- polyoxometalate." Inorganic chemistry vol. 51,16 (2012): 8784-90. doi: https://doi.org/10.1021/ic3005536
Miró P, Ling J, Qiu J, Burns PC, Gagliardi L, Cramer CJ. Experimental and computational study of a new wheel-shaped {[W5O21]3[(U(VI)O))2(μ-O2)]3}30- polyoxometalate. Inorg Chem. 2012 Aug 20;51(16):8784-90. doi: 10.1021/ic3005536. Epub 2012 Aug 02. PMID: 22857707.
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Re(I) complexes of substituted dppz: a computational and spectroscopic study.

Inorganic chemistry

van der Salm H, Fraser MG, Horvath R, Cameron SA, Barnsley JE, Sun XZ, George MW, Gordon KC.
PMID: 24559053
Inorg Chem. 2014 Mar 17;53(6):3126-40. doi: 10.1021/ic403056g. Epub 2014 Feb 21.

A series of dipyrido[3,2-a:2',3'-c]phenazine (dppz)-based ligands with electron-withdrawing substituents and their [Re(CO)3(L)Cl] and [Re(CO)3(L)(py)]PF6 complexes have been studied using Raman, resonance Raman, and transient resonance Raman (TR(2)) and time-resolved infrared (TRIR) spectroscopic techinques in conjunction with computational chemistry as...

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van der Salm H, Fraser MG, Horvath R, et al. Re(I) complexes of substituted dppz: a computational and spectroscopic study. Inorg Chem. 2014;53(6):3126-40doi: 10.1021/ic403056g.
van der Salm, H., Fraser, M. G., Horvath, R., Cameron, S. A., Barnsley, J. E., Sun, X. Z., George, M. W., & Gordon, K. C. (2014). Re(I) complexes of substituted dppz: a computational and spectroscopic study. Inorganic chemistry, 53(6), 3126-40. https://doi.org/10.1021/ic403056g
van der Salm, Holly, et al. "Re(I) complexes of substituted dppz: a computational and spectroscopic study." Inorganic chemistry vol. 53,6 (2014): 3126-40. doi: https://doi.org/10.1021/ic403056g
van der Salm H, Fraser MG, Horvath R, Cameron SA, Barnsley JE, Sun XZ, George MW, Gordon KC. Re(I) complexes of substituted dppz: a computational and spectroscopic study. Inorg Chem. 2014 Mar 17;53(6):3126-40. doi: 10.1021/ic403056g. Epub 2014 Feb 21. PMID: 24559053.
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Going beyond red with a tri- and tetracoordinate boron conjugate: intriguing near-IR optical properties and applications in anion sensing.

Inorganic chemistry

Sarkar SK, Mukherjee S, Thilagar P.
PMID: 24520954
Inorg Chem. 2014 Mar 03;53(5):2343-5. doi: 10.1021/ic402441w. Epub 2014 Feb 13.

The design and synthesis of a new tri- and tetracoordinate boron conjugate is reported. The conjugate shows broad near-IR emission (∼625-850 nm) and is found to be a selective colorimetric and ratiometric sensor for fluoride ions.

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Sarkar SK, Mukherjee S, Thilagar P. Going beyond red with a tri- and tetracoordinate boron conjugate: intriguing near-IR optical properties and applications in anion sensing. Inorg Chem. 2014;53(5):2343-5doi: 10.1021/ic402441w.
Sarkar, S. K., Mukherjee, S., & Thilagar, P. (2014). Going beyond red with a tri- and tetracoordinate boron conjugate: intriguing near-IR optical properties and applications in anion sensing. Inorganic chemistry, 53(5), 2343-5. https://doi.org/10.1021/ic402441w
Sarkar, Samir Kumar, et al. "Going beyond red with a tri- and tetracoordinate boron conjugate: intriguing near-IR optical properties and applications in anion sensing." Inorganic chemistry vol. 53,5 (2014): 2343-5. doi: https://doi.org/10.1021/ic402441w
Sarkar SK, Mukherjee S, Thilagar P. Going beyond red with a tri- and tetracoordinate boron conjugate: intriguing near-IR optical properties and applications in anion sensing. Inorg Chem. 2014 Mar 03;53(5):2343-5. doi: 10.1021/ic402441w. Epub 2014 Feb 13. PMID: 24520954.
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Preparation of ç-Cyclopentadienylcobalt(III) and ç-Cyclopentadienylnickel(IV) Complexes of the ç-7-B(10)CH(11)(3-) Carbollide Ligand.

Inorganic chemistry

Rietz RR, Dustin DF, Hawthorne MF.
PMID: 22463695
Inorg Chem. 1974 Dec 01;13(12):3046. doi: 10.1021/ic50142a606.

No abstract available.

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Rietz RR, Dustin DF, Hawthorne MF. Preparation of ç-Cyclopentadienylcobalt(III) and ç-Cyclopentadienylnickel(IV) Complexes of the ç-7-B(10)CH(11)(3-) Carbollide Ligand. Inorg Chem. 1974;13(12):3046doi: 10.1021/ic50142a606.
Rietz, R. R., Dustin, D. F., & Hawthorne, M. F. (1974). Preparation of ç-Cyclopentadienylcobalt(III) and ç-Cyclopentadienylnickel(IV) Complexes of the ç-7-B(10)CH(11)(3-) Carbollide Ligand. Inorganic chemistry, 13(12), 3046. https://doi.org/10.1021/ic50142a606
Rietz, R R, et al. "Preparation of ç-Cyclopentadienylcobalt(III) and ç-Cyclopentadienylnickel(IV) Complexes of the ç-7-B(10)CH(11)(3-) Carbollide Ligand." Inorganic chemistry vol. 13,12 (1974): 3046. doi: https://doi.org/10.1021/ic50142a606
Rietz RR, Dustin DF, Hawthorne MF. Preparation of ç-Cyclopentadienylcobalt(III) and ç-Cyclopentadienylnickel(IV) Complexes of the ç-7-B(10)CH(11)(3-) Carbollide Ligand. Inorg Chem. 1974 Dec 01;13(12):3046. doi: 10.1021/ic50142a606. PMID: 22463695.
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Preparation of ç-Cyclopentadienylcobalt(III) and ç-Cyclopentadienylnickel(IV) Complexes of the ç-7-B(10)CH(11)(3-) Carbollide Ligand.

Inorganic chemistry

Rietz RR, Dustin DF, Hawthorne MF.
PMID: 22463695
Inorg Chem. 1974 Dec 01;13(12):3046. doi: 10.1021/ic50142a606.

No abstract available.

Cite
Rietz RR, Dustin DF, Hawthorne MF. Preparation of ç-Cyclopentadienylcobalt(III) and ç-Cyclopentadienylnickel(IV) Complexes of the ç-7-B(10)CH(11)(3-) Carbollide Ligand. Inorg Chem. 1974;13(12):3046doi: 10.1021/ic50142a606.
Rietz, R. R., Dustin, D. F., & Hawthorne, M. F. (1974). Preparation of ç-Cyclopentadienylcobalt(III) and ç-Cyclopentadienylnickel(IV) Complexes of the ç-7-B(10)CH(11)(3-) Carbollide Ligand. Inorganic chemistry, 13(12), 3046. https://doi.org/10.1021/ic50142a606
Rietz, R R, et al. "Preparation of ç-Cyclopentadienylcobalt(III) and ç-Cyclopentadienylnickel(IV) Complexes of the ç-7-B(10)CH(11)(3-) Carbollide Ligand." Inorganic chemistry vol. 13,12 (1974): 3046. doi: https://doi.org/10.1021/ic50142a606
Rietz RR, Dustin DF, Hawthorne MF. Preparation of ç-Cyclopentadienylcobalt(III) and ç-Cyclopentadienylnickel(IV) Complexes of the ç-7-B(10)CH(11)(3-) Carbollide Ligand. Inorg Chem. 1974 Dec 01;13(12):3046. doi: 10.1021/ic50142a606. PMID: 22463695.
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Electron spin resonance study of o(2)(+) salts. influence of crystal field effects and relaxation.

Inorganic chemistry

Goldberg IB, Christe KO, Wilson RD.
PMID: 22463714
Inorg Chem. 1975 Dec 01;14(12):3138. doi: 10.1021/ic50154a600.

No abstract available.

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Goldberg IB, Christe KO, Wilson RD. Electron spin resonance study of o(2)(+) salts. influence of crystal field effects and relaxation. Inorg Chem. 1975;14(12):3138doi: 10.1021/ic50154a600.
Goldberg, I. B., Christe, K. O., & Wilson, R. D. (1975). Electron spin resonance study of o(2)(+) salts. influence of crystal field effects and relaxation. Inorganic chemistry, 14(12), 3138. https://doi.org/10.1021/ic50154a600
Goldberg, I B, et al. "Electron spin resonance study of o(2)(+) salts. influence of crystal field effects and relaxation." Inorganic chemistry vol. 14,12 (1975): 3138. doi: https://doi.org/10.1021/ic50154a600
Goldberg IB, Christe KO, Wilson RD. Electron spin resonance study of o(2)(+) salts. influence of crystal field effects and relaxation. Inorg Chem. 1975 Dec 01;14(12):3138. doi: 10.1021/ic50154a600. PMID: 22463714.
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Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster.

Inorganic chemistry

Gee WJ, MacLellan JG, Forsyth CM, Moubaraki B, Murray KS, Andrews PC, Junk PC.
PMID: 22857781
Inorg Chem. 2012 Aug 20;51(16):8661-3. doi: 10.1021/ic301382r. Epub 2012 Aug 02.

Sequestration of peroxide derived from molecular oxygen has resulted in the templated synthesis of a terbium picolinate cluster, isolated as a 2D sodiated network in the solid state. This first example of an air-stable rare-earth peroxide cluster represents key...

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Gee WJ, MacLellan JG, Forsyth CM, et al. Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorg Chem. 2012;51(16):8661-3doi: 10.1021/ic301382r.
Gee, W. J., MacLellan, J. G., Forsyth, C. M., Moubaraki, B., Murray, K. S., Andrews, P. C., & Junk, P. C. (2012). Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorganic chemistry, 51(16), 8661-3. https://doi.org/10.1021/ic301382r
Gee, William J, et al. "Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster." Inorganic chemistry vol. 51,16 (2012): 8661-3. doi: https://doi.org/10.1021/ic301382r
Gee WJ, MacLellan JG, Forsyth CM, Moubaraki B, Murray KS, Andrews PC, Junk PC. Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorg Chem. 2012 Aug 20;51(16):8661-3. doi: 10.1021/ic301382r. Epub 2012 Aug 02. PMID: 22857781.
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Pressure-dependent reversible increase in T(c) for the ferrimagnetic 2-D Mn(II)(TCNE)I(OH2) and 3-D Mn(II)(TCNE)(3/2)(I3)(1/2)·zTHF organic-based magnets.

Inorganic chemistry

DaSilva JG, McConnell AC, Miller JS.
PMID: 23537424
Inorg Chem. 2013 Apr 15;52(8):4629-34. doi: 10.1021/ic400250n. Epub 2013 Mar 28.

The pressure dependence of the magnetic properties of ferrimagnetic Mn(II)(TCNE)I(OH2) up to 14.05 kbar and Mn(II)(TCNE)(3/2)(I3)(1/2)·zTHF up to 14.32 kbar were studied. For Mn(II)(TCNE)I(OH2), two distinct pressure regions separated at ∼1 kbar were evident in both the temperature and...

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DaSilva JG, McConnell AC, Miller JS. Pressure-dependent reversible increase in T(c) for the ferrimagnetic 2-D Mn(II)(TCNE)I(OH2) and 3-D Mn(II)(TCNE)(3/2)(I3)(1/2)·zTHF organic-based magnets. Inorg Chem. 2013;52(8):4629-34doi: 10.1021/ic400250n.
DaSilva, J. G., McConnell, A. C., & Miller, J. S. (2013). Pressure-dependent reversible increase in T(c) for the ferrimagnetic 2-D Mn(II)(TCNE)I(OH2) and 3-D Mn(II)(TCNE)(3/2)(I3)(1/2)·zTHF organic-based magnets. Inorganic chemistry, 52(8), 4629-34. https://doi.org/10.1021/ic400250n
DaSilva, Jack G, et al. "Pressure-dependent reversible increase in T(c) for the ferrimagnetic 2-D Mn(II)(TCNE)I(OH2) and 3-D Mn(II)(TCNE)(3/2)(I3)(1/2)·zTHF organic-based magnets." Inorganic chemistry vol. 52,8 (2013): 4629-34. doi: https://doi.org/10.1021/ic400250n
DaSilva JG, McConnell AC, Miller JS. Pressure-dependent reversible increase in T(c) for the ferrimagnetic 2-D Mn(II)(TCNE)I(OH2) and 3-D Mn(II)(TCNE)(3/2)(I3)(1/2)·zTHF organic-based magnets. Inorg Chem. 2013 Apr 15;52(8):4629-34. doi: 10.1021/ic400250n. Epub 2013 Mar 28. PMID: 23537424.
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Preparation of Carboxylato-Coordinated Titanium Alkoxides from Carboxylic Anhydrides: Alkoxido Group Transfer from Metal Atom to Carbonyl Group.

European journal of inorganic chemistry

Czakler M, Artner C, Schubert U.
PMID: 23549605
Eur J Inorg Chem. 2012 Jul;2012(21):3485-3489. doi: 10.1002/ejic.201200296. Epub 2012 Jun 13.

Reaction of titanium(IV) isopropoxide, Ti(O

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Czakler M, Artner C, Schubert U. Preparation of Carboxylato-Coordinated Titanium Alkoxides from Carboxylic Anhydrides: Alkoxido Group Transfer from Metal Atom to Carbonyl Group. Eur J Inorg Chem. 2012;2012(21):3485-3489doi: 10.1002/ejic.201200296.
Czakler, M., Artner, C., & Schubert, U. (2012). Preparation of Carboxylato-Coordinated Titanium Alkoxides from Carboxylic Anhydrides: Alkoxido Group Transfer from Metal Atom to Carbonyl Group. European journal of inorganic chemistry, 2012(21), 3485-3489. https://doi.org/10.1002/ejic.201200296
Czakler, Matthias, et al. "Preparation of Carboxylato-Coordinated Titanium Alkoxides from Carboxylic Anhydrides: Alkoxido Group Transfer from Metal Atom to Carbonyl Group." European journal of inorganic chemistry vol. 2012,21 (2012): 3485-3489. doi: https://doi.org/10.1002/ejic.201200296
Czakler M, Artner C, Schubert U. Preparation of Carboxylato-Coordinated Titanium Alkoxides from Carboxylic Anhydrides: Alkoxido Group Transfer from Metal Atom to Carbonyl Group. Eur J Inorg Chem. 2012 Jul;2012(21):3485-3489. doi: 10.1002/ejic.201200296. Epub 2012 Jun 13. PMID: 23549605; PMCID: PMC3573866.
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Highly luminescent dinuclear platinum(II) complexes incorporating bis-cyclometallating pyrazine-based ligands: a versatile approach to efficient red phosphors.

Inorganic chemistry

Culham S, Lanoë PH, Whittle VL, Durrant MC, Williams JA, Kozhevnikov VN.
PMID: 24066790
Inorg Chem. 2013 Oct 07;52(19):10992-1003. doi: 10.1021/ic401131x. Epub 2013 Sep 25.

A series of luminescent dinuclear platinum(II) complexes incorporating diphenylpyrazine-based bridging ligands (L(n)H2) has been prepared. Both 2,5-diphenylpyrazine (L(2)H2) and 2,3-diphenylpyrazine (L(3)H2) are able to undergo cyclometalation of the two phenyl rings, with each metal ion binding to the two...

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Culham S, Lanoë PH, Whittle VL, et al. Highly luminescent dinuclear platinum(II) complexes incorporating bis-cyclometallating pyrazine-based ligands: a versatile approach to efficient red phosphors. Inorg Chem. 2013;52(19):10992-1003doi: 10.1021/ic401131x.
Culham, S., Lanoë, P. H., Whittle, V. L., Durrant, M. C., Williams, J. A., & Kozhevnikov, V. N. (2013). Highly luminescent dinuclear platinum(II) complexes incorporating bis-cyclometallating pyrazine-based ligands: a versatile approach to efficient red phosphors. Inorganic chemistry, 52(19), 10992-1003. https://doi.org/10.1021/ic401131x
Culham, Stacey, et al. "Highly luminescent dinuclear platinum(II) complexes incorporating bis-cyclometallating pyrazine-based ligands: a versatile approach to efficient red phosphors." Inorganic chemistry vol. 52,19 (2013): 10992-1003. doi: https://doi.org/10.1021/ic401131x
Culham S, Lanoë PH, Whittle VL, Durrant MC, Williams JA, Kozhevnikov VN. Highly luminescent dinuclear platinum(II) complexes incorporating bis-cyclometallating pyrazine-based ligands: a versatile approach to efficient red phosphors. Inorg Chem. 2013 Oct 07;52(19):10992-1003. doi: 10.1021/ic401131x. Epub 2013 Sep 25. PMID: 24066790.
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THF exchange and molecular dynamics in the series (BDI)MgX(THF), where X = Bu(n), NEt2, and OBu(t) and BDI = 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene.

Inorganic chemistry

Chisholm MH, Choojun K, Chow AS, Fraenkel G, Gallucci JC.
PMID: 24066833
Inorg Chem. 2013 Oct 07;52(19):11302-10. doi: 10.1021/ic401559b. Epub 2013 Sep 25.

The complexes (BDI)MgX(THF), where X = Bu(n), NEt2, and OBu(t), are shown to undergo THF exchange at low added concentrations of THF by a dissociative mechanism: X = Bu(n), ΔH(#) (kcal mol(-1)) = 13.4 ± 0.4 and ΔS(#) (cal...

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Chisholm MH, Choojun K, Chow AS, et al. THF exchange and molecular dynamics in the series (BDI)MgX(THF), where X = Bu(n), NEt2, and OBu(t) and BDI = 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. Inorg Chem. 2013;52(19):11302-10doi: 10.1021/ic401559b.
Chisholm, M. H., Choojun, K., Chow, A. S., Fraenkel, G., & Gallucci, J. C. (2013). THF exchange and molecular dynamics in the series (BDI)MgX(THF), where X = Bu(n), NEt2, and OBu(t) and BDI = 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. Inorganic chemistry, 52(19), 11302-10. https://doi.org/10.1021/ic401559b
Chisholm, Malcolm H, et al. "THF exchange and molecular dynamics in the series (BDI)MgX(THF), where X = Bu(n), NEt2, and OBu(t) and BDI = 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene." Inorganic chemistry vol. 52,19 (2013): 11302-10. doi: https://doi.org/10.1021/ic401559b
Chisholm MH, Choojun K, Chow AS, Fraenkel G, Gallucci JC. THF exchange and molecular dynamics in the series (BDI)MgX(THF), where X = Bu(n), NEt2, and OBu(t) and BDI = 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. Inorg Chem. 2013 Oct 07;52(19):11302-10. doi: 10.1021/ic401559b. Epub 2013 Sep 25. PMID: 24066833.
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