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Talanta. 1990 Mar;37(3):313-6. doi: 10.1016/0039-9140(90)80059-o.

Potentiometric flow-injection determination of iodide and iodine.

Talanta

D E Davey, D E Mulcahy, G R O'Connell

Affiliations

  1. School of Chemical Technology, S.A. Institute of Technology, P.O. Box 1, Ingle Farm, South Australia, 5098.

PMID: 18964943 DOI: 10.1016/0039-9140(90)80059-o

Abstract

A potentiometric flow-injection system is described, in which iodide in the concentration range 10(-6)-10(-1)M may be determined at rates of up to 360 samples/hr at a flow-rate of 17.8 ml/min. Iodine, after on-line reduction to iodide with 0.1M sodium metabisulphite, can also be determined, with a throughput of 60 samples/hr for 10(-5)-10(-3)M iodine. Analyses of two pharmaceutical preparations for iodide and iodine are reported, and the results are in reasonable agreement with titrimetric values.

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