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Chem Commun (Camb). 2012 Aug 07;48(61):7565-7. doi: 10.1039/c2cc33711h. Epub 2012 Jun 25.

Gold(I)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination.

Chemical communications (Cambridge, England)

Mari C M Higginbotham, Magnus W P Bebbington

Affiliations

  1. Institute of Chemical Sciences, Heriot-Watt University, Riccarton, Edinburgh EH14 4AS, UK.

PMID: 22728560 DOI: 10.1039/c2cc33711h

Abstract

Six-membered cyclic sulfamidates are prepared in high yields by treatment of allenic sulfamates with readily available gold(I) complexes. The reaction enables formation of N-substituted quaternary centres and complements existing processes for sulfamidate formation.

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