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Gowrisankar S, Neumann H, Gördes D, et al. A convenient and selective palladium-catalyzed aerobic oxidation of alcohols. Chemistry. 2013;19(47):15979-84doi: 10.1002/chem.201302526.
Gowrisankar, S., Neumann, H., Gördes, D., Thurow, K., Jiao, H., & Beller, M. (2013). A convenient and selective palladium-catalyzed aerobic oxidation of alcohols. Chemistry (Weinheim an der Bergstrasse, Germany), 19(47), 15979-84. https://doi.org/10.1002/chem.201302526
Gowrisankar, Saravanan, et al. "A convenient and selective palladium-catalyzed aerobic oxidation of alcohols." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 19,47 (2013): 15979-84. doi: https://doi.org/10.1002/chem.201302526
Gowrisankar S, Neumann H, Gördes D, Thurow K, Jiao H, Beller M. A convenient and selective palladium-catalyzed aerobic oxidation of alcohols. Chemistry. 2013 Nov 18;19(47):15979-84. doi: 10.1002/chem.201302526. Epub 2013 Oct 14. PMID: 24127139.
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Chemistry. 2013 Nov 18;19(47):15979-84. doi: 10.1002/chem.201302526. Epub 2013 Oct 14.

A convenient and selective palladium-catalyzed aerobic oxidation of alcohols.

Chemistry (Weinheim an der Bergstrasse, Germany)

Saravanan Gowrisankar, Helfried Neumann, Dirk Gördes, Kerstin Thurow, Haijun Jiao, Matthias Beller

Affiliations

  1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock (Germany), Fax: (+49)?381-1281-5000.

PMID: 24127139 DOI: 10.1002/chem.201302526

Abstract

An efficient procedure for the oxidation of primary and secondary alcohols to aldehydes and ketones, respectively, with molecular oxygen under ambient conditions has been achieved. By applying catalytic amounts of Pd(OAc)2 in the presence of tertiary phosphine oxides (O=PR3) as ligands, a variety of substrates are selectively oxidized without formation of ester byproducts. Spectroscopic investigations and DFT calculations suggest stabilization of the active palladium(II) catalyst by phosphine oxide ligands.

Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: alcohols; density functional calculations; oxidation; palladium; phosphine oxides

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