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Opt Express. 2014 May 05;22(9):10519-34. doi: 10.1364/OE.22.010519.

Pulsed quantum cascade laser based hypertemporal real-time headspace measurements.

Optics express

Toby K Boyson, Dylan R Rittman, Thomas G Spence, Maria E Calzada, Abhijit G Kallapur, Ian R Petersen, K Paul Kirkbride, David S Moore, Charles C Harb

PMID: 24921754 DOI: 10.1364/OE.22.010519

Abstract

Optical cavity enhancement is a highly desirable process to make sensitive direct-absorption spectroscopic measurements of unknown substances, such as explosives, illicit material, or other species of interest. This paper reports advancements in the development of real-time cavity ringdown spectroscopy over a wide-bandwidth, with the aim to make headspace measurements of molecules at trace levels. We report results of two pulsed quantum cascade systems operating between (1200 to 1320)cm(-1) and (1316 to 1613)cm(-1) that measure the headspace of nitromethane, acetonitrile, acetone, and nitroglycerin, where the spectra are obtained in less than four seconds and contain at least 150,000 spectral wavelength datapoints.

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