Advanced Search
Display options
Filter resources
Text Availability
Article type
Publication date
Species
Language
Sex
Age
Showing 1 to 3 of 3 entries
Sorted by: Best Match Show Resources per page
Studies on a new class of organogelator containing 2-anthracenecarboxylic acid: influence of gelator and solvent on stereochemistry of the photodimers.

Organic & biomolecular chemistry

Dawn A, Fujita N, Haraguchi S, Sada K, Tamaru S, Shinkai S.
PMID: 19830286
Org Biomol Chem. 2009 Nov 07;7(21):4378-85. doi: 10.1039/b910741j. Epub 2009 Aug 26.

A new class of binary organogelator (G1, G2 and G3) based on 2-anthracenecarboxylic acid (2Ac), attached noncovalently with the gelator counterpart containing a 3,4,5-tris(n-dodecyloxy)benzoylamide backbone has been developed. Among the three gelators, two (G2 and G3) are chiral containing...

Synthesis of Unprotected 2-Arylglycines by Transamination of Arylglyoxylic Acids with 2-(2-Chlorophenyl)glycine.

The Journal of organic chemistry

Inada H, Shibuya M, Yamamoto Y.
PMID: 32790313
J Org Chem. 2020 Sep 04;85(17):11047-11059. doi: 10.1021/acs.joc.0c01302. Epub 2020 Aug 18.

The transamination of α-keto acids with 2-phenylglycine is an effective methodology for directly synthesizing unprotected α-amino acids. However, the synthesis of 2-arylglycines by transamination is problematic because the corresponding products, 2-arylglycines, transaminate the starting arylglyoxylic acids. Herein, we demonstrate...

Enantioselective synthesis of (R)-2-cubylglycine including unprecedented rhodium mediated C-H insertion of cubane.

Organic & biomolecular chemistry

Houston SD, Chalmers BA, Savage GP, Williams CM.
PMID: 30644962
Org Biomol Chem. 2019 Jan 31;17(5):1067-1070. doi: 10.1039/c8ob02959h.

The first enantioselective synthesis of (R)-2-cubylglycine, an analogue of (R)-2-phenylglycine in which the phenyl ring has been replaced by cubane, is disclosed. The key step was a telescoped Strecker reaction using (S)-2-amino-2-phenylethanol as a chiral auxiliary. Exploration of an...

Showing 1 to 3 of 3 entries