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Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy).

Inorganic chemistry

Jepsen LH, Ley MB, Černý R, Lee YS, Cho YW, Ravnsbæk D, Besenbacher F, Skibsted J, Jensen TR.
PMID: 26196159
Inorg Chem. 2015 Aug 03;54(15):7402-14. doi: 10.1021/acs.inorgchem.5b00951. Epub 2015 Jul 21.

Fourteen solvent- and halide-free ammine rare-earth metal borohydrides M(BH4)3·nNH3, M = Y, Gd, Dy, n = 7, 6, 5, 4, 2, and 1, have been synthesized by a new approach, and their structures as well as chemical and physical...

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Jepsen LH, Ley MB, Černý R, et al. Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy). Inorg Chem. 2015;54(15):7402-14doi: 10.1021/acs.inorgchem.5b00951.
Jepsen, L. H., Ley, M. B., Černý, R., Lee, Y. S., Cho, Y. W., Ravnsbæk, D., Besenbacher, F., Skibsted, J., & Jensen, T. R. (2015). Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy). Inorganic chemistry, 54(15), 7402-14. https://doi.org/10.1021/acs.inorgchem.5b00951
Jepsen, Lars H, et al. "Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy)." Inorganic chemistry vol. 54,15 (2015): 7402-14. doi: https://doi.org/10.1021/acs.inorgchem.5b00951
Jepsen LH, Ley MB, Černý R, Lee YS, Cho YW, Ravnsbæk D, Besenbacher F, Skibsted J, Jensen TR. Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3 (M = Y, Gd, and Dy). Inorg Chem. 2015 Aug 03;54(15):7402-14. doi: 10.1021/acs.inorgchem.5b00951. Epub 2015 Jul 21. PMID: 26196159.
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The crystal chemistry of inorganic metal borohydrides and their relation to metal oxides.

Acta crystallographica Section B, Structural science, crystal engineering and materials

Černý R, Schouwink P.
PMID: 26634719
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2015 Dec 01;71:619-40. doi: 10.1107/S2052520615018508. Epub 2015 Dec 01.

The crystal structures of inorganic homoleptic metal borohydrides are analysed with respect to their structural prototypes found amongst metal oxides in the inorganic databases such as Pearson's Crystal Data [Villars & Cenzual (2015). Pearson's Crystal Data. Crystal Structure Database...

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Černý R, Schouwink P. The crystal chemistry of inorganic metal borohydrides and their relation to metal oxides. Acta Crystallogr B Struct Sci Cryst Eng Mater. 2015;71:619-40doi: 10.1107/S2052520615018508.
Černý, R., & Schouwink, P. (2015). The crystal chemistry of inorganic metal borohydrides and their relation to metal oxides. Acta crystallographica Section B, Structural science, crystal engineering and materials, 71619-40. https://doi.org/10.1107/S2052520615018508
Černý, Radovan, and Schouwink, Pascal. "The crystal chemistry of inorganic metal borohydrides and their relation to metal oxides." Acta crystallographica Section B, Structural science, crystal engineering and materials vol. 71 (2015): 619-40. doi: https://doi.org/10.1107/S2052520615018508
Černý R, Schouwink P. The crystal chemistry of inorganic metal borohydrides and their relation to metal oxides. Acta Crystallogr B Struct Sci Cryst Eng Mater. 2015 Dec 01;71:619-40. doi: 10.1107/S2052520615018508. Epub 2015 Dec 01. PMID: 26634719.
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Metal borohydride formation from aluminium boride and metal hydrides.

Physical chemistry chemical physics : PCCP

Møller KT, Fogh AS, Paskevicius M, Skibsted J, Jensen TR.
PMID: 27722466
Phys Chem Chem Phys. 2016 Oct 05;18(39):27545-27553. doi: 10.1039/c6cp05391b.

Metal borides are often decomposition products from metal borohydrides and thus play a role in the reverse reaction where hydrogen is absorbed. In this work, aluminium boride, AlB

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Møller KT, Fogh AS, Paskevicius M, et al. Metal borohydride formation from aluminium boride and metal hydrides. Phys Chem Chem Phys. 2016;18(39):27545-27553doi: 10.1039/c6cp05391b.
Møller, K. T., Fogh, A. S., Paskevicius, M., Skibsted, J., & Jensen, T. R. (2016). Metal borohydride formation from aluminium boride and metal hydrides. Physical chemistry chemical physics : PCCP, 18(39), 27545-27553. https://doi.org/10.1039/c6cp05391b
Møller, Kasper T, et al. "Metal borohydride formation from aluminium boride and metal hydrides." Physical chemistry chemical physics : PCCP vol. 18,39 (2016): 27545-27553. doi: https://doi.org/10.1039/c6cp05391b
Møller KT, Fogh AS, Paskevicius M, Skibsted J, Jensen TR. Metal borohydride formation from aluminium boride and metal hydrides. Phys Chem Chem Phys. 2016 Oct 05;18(39):27545-27553. doi: 10.1039/c6cp05391b. PMID: 27722466.
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Sulfurized metal borohydrides.

Dalton transactions (Cambridge, England : 2003)

Paskevicius M, Richter B, Polański M, Thompson SP, Jensen TR.
PMID: 26615897
Dalton Trans. 2016 Jan 14;45(2):639-45. doi: 10.1039/c5dt04304b.

The reactions between metal borohydrides and elemental sulfur are investigated in situ during thermal treatment and are found to be highly exothermic (up to 700 J g(-1)). These reactions are exceptionally rapid, occurring below 200 °C, also resulting in...

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Paskevicius M, Richter B, Polański M, et al. Sulfurized metal borohydrides. Dalton Trans. 2016;45(2):639-45doi: 10.1039/c5dt04304b.
Paskevicius, M., Richter, B., Polański, M., Thompson, S. P., & Jensen, T. R. (2016). Sulfurized metal borohydrides. Dalton transactions (Cambridge, England : 2003), 45(2), 639-45. https://doi.org/10.1039/c5dt04304b
Paskevicius, M, et al. "Sulfurized metal borohydrides." Dalton transactions (Cambridge, England : 2003) vol. 45,2 (2016): 639-45. doi: https://doi.org/10.1039/c5dt04304b
Paskevicius M, Richter B, Polański M, Thompson SP, Jensen TR. Sulfurized metal borohydrides. Dalton Trans. 2016 Jan 14;45(2):639-45. doi: 10.1039/c5dt04304b. PMID: 26615897.
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Shape-related optical and catalytic properties of wurtzite-type CoO nanoplates and nanorods.

Nanotechnology

Lu A, Chen Y, Zeng D, Li M, Xie Q, Zhang X, Peng DL.
PMID: 24356716
Nanotechnology. 2014 Jan 24;25(3):035707. doi: 10.1088/0957-4484/25/3/035707.

In this paper, we report the anisotropic optical and catalytic properties of wurtzite-type hexagonal CoO (h-CoO) nanocrystals, an unusual nanosized indirect semiconductor material. h-CoO nanoplates and nanorods with a divided morphology have been synthesized via facile solution methods. The...

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Lu A, Chen Y, Zeng D, et al. Shape-related optical and catalytic properties of wurtzite-type CoO nanoplates and nanorods. Nanotechnology. 2014;25(3):035707doi: 10.1088/0957-4484/25/3/035707.
Lu, A., Chen, Y., Zeng, D., Li, M., Xie, Q., Zhang, X., & Peng, D. L. (2014). Shape-related optical and catalytic properties of wurtzite-type CoO nanoplates and nanorods. Nanotechnology, 25(3), 035707. https://doi.org/10.1088/0957-4484/25/3/035707
Lu, Aolin, et al. "Shape-related optical and catalytic properties of wurtzite-type CoO nanoplates and nanorods." Nanotechnology vol. 25,3 (2014): 035707. doi: https://doi.org/10.1088/0957-4484/25/3/035707
Lu A, Chen Y, Zeng D, Li M, Xie Q, Zhang X, Peng DL. Shape-related optical and catalytic properties of wurtzite-type CoO nanoplates and nanorods. Nanotechnology. 2014 Jan 24;25(3):035707. doi: 10.1088/0957-4484/25/3/035707. PMID: 24356716.
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Complex metal borohydrides: multifunctional materials for energy storage and conversion.

Journal of physics. Condensed matter : an Institute of Physics journal

Mohtadi R, Remhof A, Jena P.
PMID: 27384871
J Phys Condens Matter. 2016 Sep 07;28(35):353001. doi: 10.1088/0953-8984/28/35/353001. Epub 2016 Jul 06.

With the limited supply of fossil fuels and their adverse effect on the climate and the environment, it has become a global priority to seek alternate sources of energy that are clean, abundant, and sustainable. While sources such as...

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Mohtadi R, Remhof A, Jena P. Complex metal borohydrides: multifunctional materials for energy storage and conversion. J Phys Condens Matter. 2016;28(35):353001doi: 10.1088/0953-8984/28/35/353001.
Mohtadi, R., Remhof, A., & Jena, P. (2016). Complex metal borohydrides: multifunctional materials for energy storage and conversion. Journal of physics. Condensed matter : an Institute of Physics journal, 28(35), 353001. https://doi.org/10.1088/0953-8984/28/35/353001
Mohtadi, Rana, et al. "Complex metal borohydrides: multifunctional materials for energy storage and conversion." Journal of physics. Condensed matter : an Institute of Physics journal vol. 28,35 (2016): 353001. doi: https://doi.org/10.1088/0953-8984/28/35/353001
Mohtadi R, Remhof A, Jena P. Complex metal borohydrides: multifunctional materials for energy storage and conversion. J Phys Condens Matter. 2016 Sep 07;28(35):353001. doi: 10.1088/0953-8984/28/35/353001. Epub 2016 Jul 06. PMID: 27384871.
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Synthesis, structure and gas-phase reactivity of the mixed silver hydride borohydride nanocluster [Ag3(μ3-H)(μ3-BH4)L(Ph)3]BF4 (L(Ph) = bis(diphenylphosphino)methane).

Nanoscale

Zavras A, Ariafard A, Khairallah GN, White JM, Mulder RJ, Canty AJ, O'Hair RA.
PMID: 26470792
Nanoscale. 2015 Nov 21;7(43):18129-37. doi: 10.1039/c5nr05690j.

Borohydrides react with silver salts to give products that span multiple scales ranging from discrete mononuclear compounds through to silver nanoparticles and colloids. The cluster cations [Ag3(H)(BH4)L3](+) are observed upon electrospray ionization mass spectrometry of solutions containing sodium borohydride,...

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Zavras A, Ariafard A, Khairallah GN, et al. Synthesis, structure and gas-phase reactivity of the mixed silver hydride borohydride nanocluster [Ag3(μ3-H)(μ3-BH4)L(Ph)3]BF4 (L(Ph) = bis(diphenylphosphino)methane). Nanoscale. 2015;7(43):18129-37doi: 10.1039/c5nr05690j.
Zavras, A., Ariafard, A., Khairallah, G. N., White, J. M., Mulder, R. J., Canty, A. J., & O'Hair, R. A. (2015). Synthesis, structure and gas-phase reactivity of the mixed silver hydride borohydride nanocluster [Ag3(μ3-H)(μ3-BH4)L(Ph)3]BF4 (L(Ph) = bis(diphenylphosphino)methane). Nanoscale, 7(43), 18129-37. https://doi.org/10.1039/c5nr05690j
Zavras, Athanasios, et al. "Synthesis, structure and gas-phase reactivity of the mixed silver hydride borohydride nanocluster [Ag3(μ3-H)(μ3-BH4)L(Ph)3]BF4 (L(Ph) = bis(diphenylphosphino)methane)." Nanoscale vol. 7,43 (2015): 18129-37. doi: https://doi.org/10.1039/c5nr05690j
Zavras A, Ariafard A, Khairallah GN, White JM, Mulder RJ, Canty AJ, O'Hair RA. Synthesis, structure and gas-phase reactivity of the mixed silver hydride borohydride nanocluster [Ag3(μ3-H)(μ3-BH4)L(Ph)3]BF4 (L(Ph) = bis(diphenylphosphino)methane). Nanoscale. 2015 Nov 21;7(43):18129-37. doi: 10.1039/c5nr05690j. PMID: 26470792.
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Modified lithium borohydrides for reversible hydrogen storage.

The journal of physical chemistry. B

Au M, Jurgensen A.
PMID: 16571023
J Phys Chem B. 2006 Apr 06;110(13):7062-7. doi: 10.1021/jp056240o.

In an attempt to develop lithium borohydrides as reversible hydrogen storage materials with high hydrogen storage capacities, the feasibility of reducing the dehydrogenation temperature of the lithium borohydride and moderating rehydrogenation conditions was explored. The lithium borohydride was modified...

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Au M, Jurgensen A. Modified lithium borohydrides for reversible hydrogen storage. J Phys Chem B. 2006;110(13):7062-7doi: 10.1021/jp056240o.
Au, M., & Jurgensen, A. (2006). Modified lithium borohydrides for reversible hydrogen storage. The journal of physical chemistry. B, 110(13), 7062-7. https://doi.org/10.1021/jp056240o
Au, Ming, and Jurgensen, Arthur. "Modified lithium borohydrides for reversible hydrogen storage." The journal of physical chemistry. B vol. 110,13 (2006): 7062-7. doi: https://doi.org/10.1021/jp056240o
Au M, Jurgensen A. Modified lithium borohydrides for reversible hydrogen storage. J Phys Chem B. 2006 Apr 06;110(13):7062-7. doi: 10.1021/jp056240o. PMID: 16571023.
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The role of interstitial H2 in hydrogen diffusion in light metal borohydrides.

Physical chemistry chemical physics : PCCP

Hao S, Sholl DS.
PMID: 20024377
Phys Chem Chem Phys. 2009 Dec 21;11(47):11106-9. doi: 10.1039/b917804j. Epub 2009 Oct 20.

First principles calculations suggest that mobility of H in solid borohydrides is dominated by neutral interstitial H(2), not charged defects.

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Hao S, Sholl DS. The role of interstitial H2 in hydrogen diffusion in light metal borohydrides. Phys Chem Chem Phys. 2009;11(47):11106-9doi: 10.1039/b917804j.
Hao, S., & Sholl, D. S. (2009). The role of interstitial H2 in hydrogen diffusion in light metal borohydrides. Physical chemistry chemical physics : PCCP, 11(47), 11106-9. https://doi.org/10.1039/b917804j
Hao, Shiqiang, and Sholl, David S. "The role of interstitial H2 in hydrogen diffusion in light metal borohydrides." Physical chemistry chemical physics : PCCP vol. 11,47 (2009): 11106-9. doi: https://doi.org/10.1039/b917804j
Hao S, Sholl DS. The role of interstitial H2 in hydrogen diffusion in light metal borohydrides. Phys Chem Chem Phys. 2009 Dec 21;11(47):11106-9. doi: 10.1039/b917804j. Epub 2009 Oct 20. PMID: 20024377.
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A series of mixed-metal borohydrides.

Angewandte Chemie (International ed. in English)

Ravnsbaek D, Filinchuk Y, Cerenius Y, Jakobsen HJ, Besenbacher F, Skibsted J, Jensen TR.
PMID: 19658149
Angew Chem Int Ed Engl. 2009;48(36):6659-63. doi: 10.1002/anie.200903030.

No abstract available.

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Ravnsbaek D, Filinchuk Y, Cerenius Y, et al. A series of mixed-metal borohydrides. Angew Chem Int Ed Engl. 2009;48(36):6659-63doi: 10.1002/anie.200903030.
Ravnsbaek, D., Filinchuk, Y., Cerenius, Y., Jakobsen, H. J., Besenbacher, F., Skibsted, J., & Jensen, T. R. (2009). A series of mixed-metal borohydrides. Angewandte Chemie (International ed. in English), 48(36), 6659-63. https://doi.org/10.1002/anie.200903030
Ravnsbaek, Dorthe, et al. "A series of mixed-metal borohydrides." Angewandte Chemie (International ed. in English) vol. 48,36 (2009): 6659-63. doi: https://doi.org/10.1002/anie.200903030
Ravnsbaek D, Filinchuk Y, Cerenius Y, Jakobsen HJ, Besenbacher F, Skibsted J, Jensen TR. A series of mixed-metal borohydrides. Angew Chem Int Ed Engl. 2009;48(36):6659-63. doi: 10.1002/anie.200903030. PMID: 19658149.
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Borane and borohydride complexes of the rare-earth elements: synthesis, structures, and butadiene polymerization catalysis.

Chemistry (Weinheim an der Bergstrasse, Germany)

Jenter J, Meyer N, Roesky PW, Thiele SK, Eickerling G, Scherer W.
PMID: 20397155
Chemistry. 2010 May 10;16(18):5472-80. doi: 10.1002/chem.200902923.

The reaction of potassium 2,5-bis[N-(2,6-diisopropylphenyl)iminomethyl]pyrrolyl [(dip(2)-pyr)K] with the borohydrides of the larger rare-earth metals, [Ln(BH(4))(3)(thf)(3)] (Ln=La, Nd), afforded the expected products [Ln(BH(4))(2)(dip(2)-pyr)(thf)(2)]. As usual, the trisborohydrides reacted like pseudohalide compounds forming KBH(4) as a by-product. To compare the reactivity...

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Jenter J, Meyer N, Roesky PW, et al. Borane and borohydride complexes of the rare-earth elements: synthesis, structures, and butadiene polymerization catalysis. Chemistry. 2010;16(18):5472-80doi: 10.1002/chem.200902923.
Jenter, J., Meyer, N., Roesky, P. W., Thiele, S. K., Eickerling, G., & Scherer, W. (2010). Borane and borohydride complexes of the rare-earth elements: synthesis, structures, and butadiene polymerization catalysis. Chemistry (Weinheim an der Bergstrasse, Germany), 16(18), 5472-80. https://doi.org/10.1002/chem.200902923
Jenter, Jelena, et al. "Borane and borohydride complexes of the rare-earth elements: synthesis, structures, and butadiene polymerization catalysis." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 16,18 (2010): 5472-80. doi: https://doi.org/10.1002/chem.200902923
Jenter J, Meyer N, Roesky PW, Thiele SK, Eickerling G, Scherer W. Borane and borohydride complexes of the rare-earth elements: synthesis, structures, and butadiene polymerization catalysis. Chemistry. 2010 May 10;16(18):5472-80. doi: 10.1002/chem.200902923. PMID: 20397155.
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Borohydrides from organic hydrides: reactions of Hantzsch's esters with B(C(6)F(5))(3).

Chemistry (Weinheim an der Bergstrasse, Germany)

Webb JD, Laberge VS, Geier SJ, Stephan DW, Crudden CM.
PMID: 20309967
Chemistry. 2010 Apr 26;16(16):4895-902. doi: 10.1002/chem.200903005.

We report herein that the reaction between a series of Hantzsch's ester analogues 1 a-d with the Lewis acidic species B(C(6)F(5))(3) results in facile transfer of hydride to boron. The main products of this reaction are pyridinium borohydride salts...

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Webb JD, Laberge VS, Geier SJ, et al. Borohydrides from organic hydrides: reactions of Hantzsch's esters with B(C(6)F(5))(3). Chemistry. 2010;16(16):4895-902doi: 10.1002/chem.200903005.
Webb, J. D., Laberge, V. S., Geier, S. J., Stephan, D. W., & Crudden, C. M. (2010). Borohydrides from organic hydrides: reactions of Hantzsch's esters with B(C(6)F(5))(3). Chemistry (Weinheim an der Bergstrasse, Germany), 16(16), 4895-902. https://doi.org/10.1002/chem.200903005
Webb, Jonathan D, et al. "Borohydrides from organic hydrides: reactions of Hantzsch's esters with B(C(6)F(5))(3)." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 16,16 (2010): 4895-902. doi: https://doi.org/10.1002/chem.200903005
Webb JD, Laberge VS, Geier SJ, Stephan DW, Crudden CM. Borohydrides from organic hydrides: reactions of Hantzsch's esters with B(C(6)F(5))(3). Chemistry. 2010 Apr 26;16(16):4895-902. doi: 10.1002/chem.200903005. PMID: 20309967.
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Showing 1 to 12 of 119 entries