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Direct Amine-Catalyzed Enantioselective Synthesis of Pentacyclic Dibenzo[.

The Journal of organic chemistry

Yadav J, Pawar AP, Nagare YK, Iype E, Rangan K, Ohshita J, Kumar D, Kumar I.
PMID: 33030896
J Org Chem. 2020 Nov 06;85(21):14094-14108. doi: 10.1021/acs.joc.0c02141. Epub 2020 Oct 08.

A direct protocol for the asymmetric synthesis of dibenzoxazepine/thiazepine-fused [2.2.2] isoquinuclidines is developed. The reaction proceeds through a proline-catalyzed direct Mannich reaction followed by an intramolecular aza-Michael cascade sequence between 2-cyclohexene-1-one and various tricyclic imines, like dibenzoxazepines/thiazepines, as an...

Cite
Yadav J, Pawar AP, Nagare YK, et al. Direct Amine-Catalyzed Enantioselective Synthesis of Pentacyclic Dibenzo[. J Org Chem. 2020;85(21):14094-14108doi: 10.1021/acs.joc.0c02141.
Yadav, J., Pawar, A. P., Nagare, Y. K., Iype, E., Rangan, K., Ohshita, J., Kumar, D., & Kumar, I. (2020). Direct Amine-Catalyzed Enantioselective Synthesis of Pentacyclic Dibenzo[. The Journal of organic chemistry, 85(21), 14094-14108. https://doi.org/10.1021/acs.joc.0c02141
Yadav, Jyothi, et al. "Direct Amine-Catalyzed Enantioselective Synthesis of Pentacyclic Dibenzo[." The Journal of organic chemistry vol. 85,21 (2020): 14094-14108. doi: https://doi.org/10.1021/acs.joc.0c02141
Yadav J, Pawar AP, Nagare YK, Iype E, Rangan K, Ohshita J, Kumar D, Kumar I. Direct Amine-Catalyzed Enantioselective Synthesis of Pentacyclic Dibenzo[. J Org Chem. 2020 Nov 06;85(21):14094-14108. doi: 10.1021/acs.joc.0c02141. Epub 2020 Oct 08. PMID: 33030896.
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