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Copper-Catalyzed C(sp(2))-H Difluoroalkylation of Aldehyde Derived Hydrazones with Diboron as Reductant.

The Journal of organic chemistry

Ke M, Song Q.
PMID: 27022838
J Org Chem. 2016 May 06;81(9):3654-64. doi: 10.1021/acs.joc.6b00324. Epub 2016 Apr 07.

An efficient and general method for C(sp(2))-H difluoroalkylation of aldehyde derived hydrazones via a Cu(II)/B2pin2-catalyzed reaction between difluoroalkyl bromides and hydrazones was developed. In this reaction, both aromatic and aliphatic difluoroalkylated aldehyde derived hydrazones could be achieved in good...

Halide abstraction from halogenated acetate ligands by actinyls: a competition between bond breaking and bond making.

The journal of physical chemistry. A

Dau PD, Gibson JK.
PMID: 25766197
J Phys Chem A. 2015 Apr 02;119(13):3218-24. doi: 10.1021/acs.jpca.5b00952. Epub 2015 Mar 20.

Transfer of halogen atoms from halogenated acetate ligands, CX3CO2 (X = F, Cl, Br), to actinyls, AnO2(2+) (An = U, Np, Pu) is stimulated by collision-induced dissociation (CID) in a quadrupole ion trap. CID of [AnO2(CF3CO2)3](-) complexes results exclusively...

Showing 1 to 2 of 2 entries