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Fractionation of the platinum-group elements during mantle melting

Science interventions

Ballhaus C, Holzheid A.
GSID: -9tfI649Rg8J
C Bockrath, C Ballhaus, A Holzheid - Science, 2004 - science.org

Experiments in sulfide-silicate systems demonstrate that two sulfide phases are stable in the asthenospheric upper mantle: a crystalline osmium-iridiumruthenium–enriched monosulfide …

Migration of single iridium atoms and tri-iridium clusters on MgO surfaces: Aberration-corrected STEM imaging and ab initio calculations

Theoretical frames STEM

Curtiss LA, Han CW, Iddir H, Uzun A.
GSID: 1rfZieyKSZkJ
CW Han, H Iddir, A Uzun, LA Curtiss… - The Journal of …, 2015 - ACS Publications

… in STEM, resulting in remarkably high spatial resolution and signal-to-noise ratios. (14) More important, the high signal-to-noise ratios in STEM imaging enable high frame … theoretical …

First practical cross-alkylation of primary alcohols with a new and recyclable impregnated iridium on magnetite catalyst.

Chemical communications (Cambridge, England)

Cano R, Yus M, Ramón DJ.
PMID: 22732869
Chem Commun (Camb). 2012 Aug 07;48(61):7628-30. doi: 10.1039/c2cc33101b. Epub 2012 Jun 26.

A new impregnated iridium on magnetite catalyst has been prepared, characterized, used and recycled, up to ten times with practically the same activity, for the first practical cross-alkylation of primary alcohols. The catalyst showed a wide reaction scope, is...

Iridium phosphors with peripheral triphenylamine encapsulation: highly efficient solution-processed red electrophosphorescence.

Chemical communications (Cambridge, England)

Zhu M, Li Y, Hu S, Li C, Yang C, Wu H, Qin J, Cao Y.
PMID: 22306807
Chem Commun (Camb). 2012 Mar 11;48(21):2695-7. doi: 10.1039/c2cc17515k. Epub 2012 Feb 03.

The peripheral triphenylamine-encapsulated red-emitting iridium(III) complexes have been designed and synthesized. External quantum efficiency over 15% has been realized in single-layer polymer light-emitting diodes, which is the highest ever reported for solution-processed red phosphorescence.

Metal-templated chiral Brønsted base organocatalysis.

Nature communications

Ma J, Ding X, Hu Y, Huang Y, Gong L, Meggers E.
PMID: 25072163
Nat Commun. 2014 Jul 29;5:4531. doi: 10.1038/ncomms5531.

Inert octahedral chiral-at-metal complexes are an emerging class of asymmetric catalysts that exploit the globular, rigid nature and stereochemical options of octahedral compounds. While the central transition metal serves as a structural anchorpoint and provides metal centrochirality, catalysis is...

New possible mode of ligand-metal cooperation in PC(sp3)P pincer complexes.

Dalton transactions (Cambridge, England : 2003)

Musa S, Romm R, Azerraf C, Kozuch S, Gelman D.
PMID: 21431178
Dalton Trans. 2011 Sep 21;40(35):8760-3. doi: 10.1039/c1dt10167f. Epub 2011 Mar 23.

Ligand-metal cooperation in iridium and platinum complexes bearing tricyclic dibenzobarrelene-based PC(sp(3))P pincer ligands is discussed. We demonstrated that the carbon-metal bond in these complexes may be efficiently cleaved and regenerated via 1,2-addition/elimination reactions.

Pure red phosphorescent organic light-emitting diodes made of iridium(III) complex with thiophene-quinoline ligand.

Journal of nanoscience and nanotechnology

Lim JM, Kwon JY, Xu F, Kim HU, Hwang DH.
PMID: 24266181
J Nanosci Nanotechnol. 2013 Dec;13(12):8007-10. doi: 10.1166/jnn.2013.8152.

A cyclometalated iridium(II) complex, bis(2-thiophen-2-yl-quinolinato)(acetoacetonate)iridium(II) [(tq)2Ir(III)(acac)] was synthesized for use in phosphorescent organic light-emitting diodes. The photophysical and electrochemical properties of the iridium(Ill) complex were characterized by UV-visible absorption, photoluminescence, and cyclic voltammetry. The maximum UV-visible absorption of (tq)2Ir(acac)...

Heterogeneous Catalysis for Water Oxidation by an Iridium Complex Immobilized on Bipyridine-Periodic Mesoporous Organosilica.

Angewandte Chemie (International ed. in English)

Liu X, Maegawa Y, Goto Y, Hara K, Inagaki S.
PMID: 27168492
Angew Chem Int Ed Engl. 2016 Jul 04;55(28):7943-7. doi: 10.1002/anie.201601453. Epub 2016 May 11.

Heterogenization of metal-complex catalysts for water oxidation without loss of their catalytic activity is important for the development of devices simulating photosynthesis. In this study, efficient heterogeneous iridium complexes for water oxidation were prepared using bipyridine-bridged periodic mesoporous organosilica...

Improved efficiency of red phosphorescent organic light-emitting diodes with combination of heterojunction and mixed host structure.

Journal of nanoscience and nanotechnology

Lim DH, Lee SJ, Koo JR, Kim BY, Shin HS, Lee KH, Lee SY, Kim WY, Yoon SS, Kim YK.
PMID: 25936044
J Nanosci Nanotechnol. 2014 Aug;14(8):5998-6001. doi: 10.1166/jnn.2014.8442.

We report an improvement of efficiency in red phosphorescent organic light-emitting diodes (PHOLEDs) based on a combination of heterojunction (HJ) structure and mixed host (MH) system using a phosphorescent red emitter: bis(2-phenylquinolinato)-acetylacetonate iridium III [Ir(pq)2(acac)] doped in 4,4,N,N'-dicarbazolebiphenyl (CBP)...

Photoswitchable azobenzene-appended iridium(iii) complexes.

Dalton transactions (Cambridge, England : 2003)

Pérez-Miqueo J, Altube A, García-Lecina E, Tron A, McClenaghan ND, Freixa Z.
PMID: 27460186
Dalton Trans. 2016 Sep 21;45(35):13726-41. doi: 10.1039/c6dt01817c. Epub 2016 Jul 27.

Iridium(iii) cyclometalated complexes have been used as models to study the effect that extended conjugation and substitution pattern has on the photochromic behavior of azobenzene-appended 2-phenylpyridyl (ppy) ligands. For this purpose four azobenzene-containing ppy ligands were synthesized. With these...

Synthesis of Quinolines via a Metal-Catalyzed Dehydrogenative N-Heterocyclization.

Chemical record (New York, N.Y.)

Chelucci G, Porcheddu A.
PMID: 27524555
Chem Rec. 2017 Feb;17(2):200-216. doi: 10.1002/tcr.201600083. Epub 2016 Aug 15.

Efficient ruthenium-, rhodium-, palladium-, copper- and iridium-catalysed methodologies have been recently developed for the synthesis of quinolines by the reaction of 2-aminobenzyl alcohols with carbonyl compounds (aldehydes and ketones) or the related alcohols. The reaction is assumed to proceed...

Boosting water oxidation layer-by-layer.

Physical chemistry chemical physics : PCCP

Hidalgo-Acosta JC, Scanlon MD, Méndez MA, Amstutz V, Vrubel H, Opallo M, Girault HH.
PMID: 26977761
Phys Chem Chem Phys. 2016 Apr 07;18(13):9295-304. doi: 10.1039/c5cp06890h. Epub 2016 Mar 15.

Electrocatalysis of water oxidation was achieved using fluorinated tin oxide (FTO) electrodes modified with layer-by-layer deposited films consisting of bilayers of negatively charged citrate-stabilized IrO2 NPs and positively charged poly(diallyldimethylammonium chloride) (PDDA) polymer. The IrO2 NP surface coverage can...

Showing 1 to 12 of 4396 entries