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Stereocontrol in organic synthesis using silicon-containing compounds. Studies directed towards the synthesis of ebelactone A.

Organic & biomolecular chemistry

Archibald SC, Barden DJ, Bazin JF, Fleming I, Foster CF, Mandal AK, Mandal AK, Parker D, Takaki K, Ware AC, Williams AR, Zwicky AB.
PMID: 15034629
Org Biomol Chem. 2004 Apr 07;2(7):1051-64. doi: 10.1039/b316899a. Epub 2004 Mar 05.

Several approaches to the synthesis of ebelactone A 2 are described, culminating in the synthesis of the benzenesulfonate of 2-epi-ebelactone A 161. All the approaches were based on three fragments A, B and C, originally defined in general terms...

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