Advanced Search
Display options
Filter resources
Text Availability
Article type
Publication date
Species
Language
Sex
Age
Showing 1 to 12 of 125 entries
Sorted by: Best Match Show Resources per page
Separation of ions by alteration of the concentration of the ligand in a discontinuous countercurrent extraction system.

Talanta

Boswell CR, Brooks RR.
PMID: 18960146
Talanta. 1967 Jun;14(6):655-8. doi: 10.1016/0039-9140(67)80032-8.

A new technique in Craig-type liquid-liquid, discontinuous, countercurrent solvent extraction was developed. In this, the ligand concentration in the extraction train was altered at several points, causing non-equivalent changes in the extractability of the ions being separated. This allowed...

Sensitive assay for oxygen solubility in molten alkali metal carbonates by indirect flame atomic absorption spectrometric Cr(VI) determination.

Talanta

Scaccia S, Frangini S.
PMID: 18969674
Talanta. 2004 Oct 20;64(3):791-7. doi: 10.1016/j.talanta.2004.03.026.

A precise and accurate indirect analytical method for the assessment of O(2) solubility in molten (Li(0.62)K(0.38))(2)CO(3) and (Li(0.52)Na(0.48))(2)CO(3) is described. The method is based on the oxidation of Cr(2)(SO(4))(3) (added in excess to the melt) by the oxygenate species,...

Spectrophotometric determination of saccharin in different materials by a solvent extraction method using Nile Blue as reagent.

Talanta

Cordoba MH, Garcia IL, Sanchez-Pedreño C.
PMID: 18963851
Talanta. 1985 Apr;32(4):325-7. doi: 10.1016/0039-9140(85)80088-6.

In a slightly acidic medium (sodium acetate-acetic acid buffer, pH 4) saccharin and Nile Blue form an ion-association compound which is extractable into methyl isobutyl ketone and allows the spectrophotometric determination of saccharin. At 630 nm Beer's law is...

Methyl isobutyl ketone extraction of iodide complexes from sulphuric acid-potassium iodide media and back-extraction into an aqueous phase.

Talanta

Donaldson EM, Wang M.
PMID: 18964030
Talanta. 1986 Jan;33(1):35-44. doi: 10.1016/0039-9140(86)80010-8.

The methyl isobutyl ketone extraction of 15 elements (Cu, Ag, Zn, Cd, In, Tl, Ge, Sn, As, Sb, Bi, Se, Te, Mo and Pd) as iodide complexes from 0.1-5 M sulphuric acid/0.01-0.5M potassium iodide media has been studied. At...

Solvent extraction of Cd(II) with N-cyclohexyl-N-nitrosohydroxylamine and 4-methylpyridine into methyl isobutyl ketone.

Talanta

Rauret G, Pineda L, Casas R, Compaño R, Sanchez-Reyes A.
PMID: 18964544
Talanta. 1988 May;35(5):413-8. doi: 10.1016/0039-9140(88)80038-9.

The distribution equilibria of the complexes cadmium-cnha and cadmium-cnha-4-methylpyridine in the water-methyl isobutyl ketone system have been studied at 25 degrees , by using (109)Cd as a radiotracer to measure the metal distribution ratio. A very sensitive method for...

Masking of iron with fluoride in the extractive atomic-absorption spectrometric determination of chromium in steel.

Talanta

Fogg AG, Soleymanloo S, Burns DT.
PMID: 18961681
Talanta. 1975 Jun;22(6):541-3. doi: 10.1016/0039-9140(75)80050-6.

Chromium in steel is determined by oxidation to dichromate, extraction into methyl isobutyl ketone from 1-3 M hydrochloric acid, and atomic-absorption measurements on the extract. The interference of iron in the atomic absorption is eliminated by using fluoride to...

Selective determination of arsenic(III) and arsenic(V) with ammonium pyrrolidinedithiocarbamate, sodium diethyldithiocarbamate and dithizone by means of flameless atomic-absorption spectrophotometry with a carbon-tube atomizer.

Talanta

Kamada T.
PMID: 18961992
Talanta. 1976 November - December;23(11):835-9. doi: 10.1016/0039-9140(76)80096-3.

The extraction behaviour of arsenic(III) and arsenic(V) with ammonium pyrrolidinedithiocarbamate, sodium diethyldithiocarbamate and dithizone in organic solvents has been investigated by means of nameless atomic-absorption spectrophotometry with a carbon-tube atomizer. The selective extraction of arsenic(III) and differential determination of...

Extractive spectrophotometric determination of uranium with Malachite Green.

Talanta

Dubey SC, Nadkarni MN.
PMID: 18962080
Talanta. 1977 Apr;24(4):266-7. doi: 10.1016/0039-9140(77)80149-5.

A sensitive spectrophotometric method based on the extraction of a uranium-benzoate-Malachite Green complex by chlorobenzene is described. The absorption maximum is at 635 nm and the molar absorptivity is 8.3 x 10(4) 1 mole(-1), cm(-1). A preliminary separation of...

Determination of silica in silicates by formation of 12-molybdosilicic acid and redox titration of molybdenum(III).

Talanta

Ohlweiler OA, Meditsch JO.
PMID: 18962167
Talanta. 1977 Oct;24(10):652-4. doi: 10.1016/0039-9140(77)80114-8.

An indirect titrimetric method for the determination of silica in silicates is described. A boron trioxide-lithium carbonate (10:1) mixture is used as flux and the melt is dissolved in an acidic molybdate solution to form 12-molybdosilicic acid. The yellow...

Separation of molybdenum from interfering elements by extraction as phosphomolybdenum blue.

Talanta

Yatirajam V, Ram J.
PMID: 18961358
Talanta. 1973 Sep;20(9):885-90. doi: 10.1016/0039-9140(73)80204-8.

A simple method is described for the separation of molybdenum from titanium, zirconium, chromium, manganese, iron, cobalt, nickel, uranium and aluminium in a wide variety of samples in

Determination of traces of Mo in soils and geological materials by solvent extraction of the molybdenum-thiocyanate complex and atomic absorption.

Talanta

Kim CH, Owens CM, Smythe LE.
PMID: 18961481
Talanta. 1974 Jun;21(6):445-54. doi: 10.1016/0039-9140(74)80174-8.

Comprehensive studies of the extraction of the molybdenum-thiocyanate complex with methyl isobutyl ketone have resulted in an improved method for the determination of traces of molybdenum in soils and geological materials by atomic-absorption spectroscopy. The method is applicable in...

Pre-concentration of trace metals from sea-water for determination by graphite-furnace atomic-absorption spectrometry.

Talanta

Sturgeon RE, Berman SS, Desaulniers A, Russell DS.
PMID: 18962623
Talanta. 1980 Feb;27(2):85-94. doi: 10.1016/0039-9140(80)80023-3.

Determination of Cd, Zn, Pb, Cu, Fe, Mn, Co, Cr and Ni in coastal sea-water by graphite-furnace atomic-absorption spectrometry after preconcentration by solvent extraction and use of a chelating ion-exchange resin is described. Following the extraction of the pyrrolidine-N-carbodithioate...

Showing 1 to 12 of 125 entries