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Nitrosylation of Octaethylporphyrin Osmium Complexes with Alkyl Nitrites and Thionitrites: Molecular Structures of Three Osmium Porphyrin Derivatives.

Inorganic chemistry

Chen L, Khan MA, Richter-Addo GB.
PMID: 11670305
Inorg Chem. 1998 Feb 09;37(3):533-540. doi: 10.1021/ic9708576.

(OEP)Os(CO) reacts with n-butyl nitrite to give, after workup, the (OEP)Os(NO)(O-n-Bu) trans addition product (OEP = octaethylporphyrinato dianion). Similarly, the reaction of (OEP)Os(CO) or [(OEP)Os](2) with isoamyl nitrite gives the corresponding nitrosyl alkoxide, (OEP)Os(NO)(O-i-C(5)H(11)). The related reactions of (OEP)Os(CO)...

Infrared laser spectroscopy of the n-propyl and i-propyl radicals: Stretch-bend Fermi coupling in the alkyl CH stretch region.

The Journal of chemical physics

Franke PR, Tabor DP, Moradi CP, Douberly GE, Agarwal J, Schaefer HF, Sibert EL.
PMID: 27984908
J Chem Phys. 2016 Dec 14;145(22):224304. doi: 10.1063/1.4971239.

The n-propyl and i-propyl radicals were generated in the gas phase via pyrolysis of n-butyl nitrite [CH

Photolysis of n-butyl nitrite and isoamyl nitrite at 355 nm: a time-resolved Fourier transform infrared emission spectroscopy and ab initio study.

The Journal of chemical physics

Ji M, Zhen J, Zhang Q, Chen Y.
PMID: 19425783
J Chem Phys. 2009 May 07;130(17):174314. doi: 10.1063/1.3129806.

We report on the photodissociation dynamics study of n-butyl nitrite and isoamyl nitrite by means of time-resolved Fourier transform infrared (TR-FTIR) emission spectroscopy. The obtained TR-FTIR emission spectra of the nascent NO fragments produced in the 355 nm laser...

Photodissociation dynamics of alkyl nitrites at 266 and 355 nm: the OH product channel.

The journal of physical chemistry. A

Yue XF, Sun JL, Yin HM, Wei Q, Han KL.
PMID: 19284722
J Phys Chem A. 2009 Apr 09;113(14):3303-10. doi: 10.1021/jp810731d.

Photodissociation of methyl nitrite and n-butyl nitrite at 266 and 355 nm has been investigated in the gas phase at room temperature. OH photoproducts were observed, and their internal state distributions were measured by the one-photon laser-induced fluorescence (LIF)...

Showing 1 to 4 of 4 entries