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Sandee AJ, van Der Veen LA, Reek JN, et al. A Robust, Environmentally Benign Catalyst for Highly Selective Hydroformylation. Angew Chem Int Ed Engl. 1999;38(21):3231-3235
Sandee, A. J., van Der Veen LA, Reek, J. N., Kamer, P. C., Lutz, M., Spek, A. L., & van Leeuwen PW. (1999). A Robust, Environmentally Benign Catalyst for Highly Selective Hydroformylation. Angewandte Chemie (International ed. in English), 38(21), 3231-3235.
Sandee, et al. "A Robust, Environmentally Benign Catalyst for Highly Selective Hydroformylation." Angewandte Chemie (International ed. in English) vol. 38,21 (1999): 3231-3235.
Sandee AJ, van Der Veen LA, Reek JN, Kamer PC, Lutz M, Spek AL, van Leeuwen PW. A Robust, Environmentally Benign Catalyst for Highly Selective Hydroformylation. Angew Chem Int Ed Engl. 1999 Nov 02;38(21):3231-3235. PMID: 10556912.
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Angew Chem Int Ed Engl. 1999 Nov 02;38(21):3231-3235.

A Robust, Environmentally Benign Catalyst for Highly Selective Hydroformylation.

Angewandte Chemie (International ed. in English)

Sandee, van Der Veen LA, Reek, Kamer, Lutz, Spek, van Leeuwen PW

Affiliations

  1. Institute of Molecular Chemistry, Nieuwe Achtergracht 166 1018 WV Amsterdam (The Netherlands).

PMID: 10556912

Abstract

By a sol-gel process a rhodium complex containing a diphosphane with a large natural P-Rh-P bite angle is covalently anchored in a silica matrix (see picture). The immobilized catalyst is a very selective hydroformylation catalyst that is completely and conveniently separated from the product and can be reused in numerous cycles.

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