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Reetz MT, Westermann E. Phosphane-Free Palladium-Catalyzed Coupling Reactions: The Decisive Role of Pd Nanoparticles. Angew Chem Int Ed Engl. 2000;39(1):165-168doi: 10.1002/(sici)1521-3773(20000103)39:1<165::aid-anie165>3.0.co;2-b.
Reetz, M. T., & Westermann, E. (2000). Phosphane-Free Palladium-Catalyzed Coupling Reactions: The Decisive Role of Pd Nanoparticles. Angewandte Chemie (International ed. in English), 39(1), 165-168. https://doi.org/10.1002/(sici)1521-3773(20000103)39:1<165::aid-anie165>3.0.co;2-b
Reetz, and Westermann. "Phosphane-Free Palladium-Catalyzed Coupling Reactions: The Decisive Role of Pd Nanoparticles." Angewandte Chemie (International ed. in English) vol. 39,1 (2000): 165-168. doi: https://doi.org/10.1002/(sici)1521-3773(20000103)39:1<165::aid-anie165>3.0.co;2-b
Reetz MT, Westermann E. Phosphane-Free Palladium-Catalyzed Coupling Reactions: The Decisive Role of Pd Nanoparticles. Angew Chem Int Ed Engl. 2000 Jan;39(1):165-168. doi: 10.1002/(sici)1521-3773(20000103)39:1<165::aid-anie165>3.0.co;2-b. PMID: 10649362.
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Angew Chem Int Ed Engl. 2000 Jan;39(1):165-168. doi: 10.1002/(sici)1521-3773(20000103)39:1<165::aid-anie165>3.0.co;2-b.

Phosphane-Free Palladium-Catalyzed Coupling Reactions: The Decisive Role of Pd Nanoparticles.

Angewandte Chemie (International ed. in English)

Reetz, Westermann

Affiliations

  1. Max-Planck-Institut für Kohlenforschung Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany).

PMID: 10649362 DOI: 10.1002/(sici)1521-3773(20000103)39:1<165::aid-anie165>3.0.co;2-b

Abstract

Nanosized palladium colloids, generated in situ by reduction of Pd(II) to Pd(0) [Eq. (a)], are involved in the catalysis of phosphane-free Heck and Suzuki reactions with simple palladium salts such as PdCl(2) or Pd(OAc)(2), as demonstrated by transmission electron microscopic investigations.

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