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Weissbuch I, Baxter PN, Kuzmenko I, et al. Oriented crystalline monolayers and bilayers of 2 x 2 silver(I) grid architectures at the air-solution interface: their assembly and crystal structure elucidation. Chemistry. 2000;6(4):725-34doi: 10.1002/(sici)1521-3765(20000218)6:4<725::aid-chem725>3.0.co;2-e.
Weissbuch, I., Baxter, P. N., Kuzmenko, I., Cohen, H., Cohen, S., Kjaer, K., Howes, P. B., Als-Nielsen, J., Lehn, J. M., Leiserowitz, L., & Lahav, M. (2000). Oriented crystalline monolayers and bilayers of 2 x 2 silver(I) grid architectures at the air-solution interface: their assembly and crystal structure elucidation. Chemistry (Weinheim an der Bergstrasse, Germany), 6(4), 725-34. https://doi.org/10.1002/(sici)1521-3765(20000218)6:4<725::aid-chem725>3.0.co;2-e
Weissbuch, et al. "Oriented crystalline monolayers and bilayers of 2 x 2 silver(I) grid architectures at the air-solution interface: their assembly and crystal structure elucidation." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 6,4 (2000): 725-34. doi: https://doi.org/10.1002/(sici)1521-3765(20000218)6:4<725::aid-chem725>3.0.co;2-e
Weissbuch I, Baxter PN, Kuzmenko I, Cohen H, Cohen S, Kjaer K, Howes PB, Als-Nielsen J, Lehn JM, Leiserowitz L, Lahav M. Oriented crystalline monolayers and bilayers of 2 x 2 silver(I) grid architectures at the air-solution interface: their assembly and crystal structure elucidation. Chemistry. 2000 Feb 18;6(4):725-34. doi: 10.1002/(sici)1521-3765(20000218)6:4<725::aid-chem725>3.0.co;2-e. PMID: 10807183.
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Chemistry. 2000 Feb 18;6(4):725-34. doi: 10.1002/(sici)1521-3765(20000218)6:4<725::aid-chem725>3.0.co;2-e.

Oriented crystalline monolayers and bilayers of 2 x 2 silver(I) grid architectures at the air-solution interface: their assembly and crystal structure elucidation.

Chemistry (Weinheim an der Bergstrasse, Germany)

Weissbuch, Baxter, Kuzmenko, Cohen, Cohen, Kjaer, Howes, Als-Nielsen, Lehn, Leiserowitz, Lahav

Affiliations

  1. Department of Materials and Interfaces, The Weizmann Institute of Science, Rehovot, Israel. [email protected]

PMID: 10807183 DOI: 10.1002/(sici)1521-3765(20000218)6:4<725::aid-chem725>3.0.co;2-e

Abstract

Oriented crystalline monolayers, approximately 14 A thick, of a 2 x 2 Ag+ grid complex, self-assembled at the air-solution interface starting from an water-insoluble ligand 3,6-bis[2-(6-phenylpyridine)]pyridazine spread on silver-ion-containing solutions, were examined by grazing-incidence X-ray diffraction and specular X-ray reflectivity using synchrotron radiation. The monolayer structure was refined, including a determination of the positions of the counter-ions, with the SHELX-97 computer program. The monolayers were transferred from the interface onto various solid supports and visualized by scanning force microscopy, and characterized by X-ray photoelectron spectroscopy in terms of molecular structure. On surface compression, the initial self-assembled monolayer undergoes a transition to a crystalline bilayer in which the two layers, almost retaining the original arrangement, are in registry. Such a phase transition is of relevance to the understanding of crystal nucleation.

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