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Billard T, Bruns S, Langlois BR. New stable reagents for the nucleophilic trifluoromethylation. 1. Trifluoromethylation Of carbonyl compounds with N-formylmorpholine derivatives. Org Lett. 2000;2(14):2101-3doi: 10.1021/ol005987o.
Billard, T., Bruns, S., & Langlois, B. R. (2000). New stable reagents for the nucleophilic trifluoromethylation. 1. Trifluoromethylation Of carbonyl compounds with N-formylmorpholine derivatives. Organic letters, 2(14), 2101-3. https://doi.org/10.1021/ol005987o
Billard, et al. "New stable reagents for the nucleophilic trifluoromethylation. 1. Trifluoromethylation Of carbonyl compounds with N-formylmorpholine derivatives." Organic letters vol. 2,14 (2000): 2101-3. doi: https://doi.org/10.1021/ol005987o
Billard T, Bruns S, Langlois BR. New stable reagents for the nucleophilic trifluoromethylation. 1. Trifluoromethylation Of carbonyl compounds with N-formylmorpholine derivatives. Org Lett. 2000 Jul 13;2(14):2101-3. doi: 10.1021/ol005987o. PMID: 10891240.
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Org Lett. 2000 Jul 13;2(14):2101-3. doi: 10.1021/ol005987o.

New stable reagents for the nucleophilic trifluoromethylation. 1. Trifluoromethylation Of carbonyl compounds with N-formylmorpholine derivatives.

Organic letters

Billard, Bruns, Langlois

Affiliations

  1. Synthese, Electrosynthese et Reactivite des Composes Organiques Fluores (SERCOF), UMR CNRS 5622, Universite Claude Bernard-Lyon I, 43 Bd du 11 Novembre 1918, F-69622 Villeurbanne, France.

PMID: 10891240 DOI: 10.1021/ol005987o

Abstract

A new stable equivalent of the trifluoromethyl anion has been synthesized from fluoroform. It reacts with nonenolizable carbonyl compounds such as the Ruppert's reagent.

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