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Gruber AS, Zim D, Ebeling G, et al. Sulfur-containing palladacycles as catalyst precursors for the Heck reaction. Org Lett. 2000;2(9):1287-90doi: 10.1021/ol0057277.
Gruber, A. S., Zim, D., Ebeling, G., Monteiro, A. L., & Dupont, J. (2000). Sulfur-containing palladacycles as catalyst precursors for the Heck reaction. Organic letters, 2(9), 1287-90. https://doi.org/10.1021/ol0057277
Gruber, et al. "Sulfur-containing palladacycles as catalyst precursors for the Heck reaction." Organic letters vol. 2,9 (2000): 1287-90. doi: https://doi.org/10.1021/ol0057277
Gruber AS, Zim D, Ebeling G, Monteiro AL, Dupont J. Sulfur-containing palladacycles as catalyst precursors for the Heck reaction. Org Lett. 2000 May 04;2(9):1287-90. doi: 10.1021/ol0057277. PMID: 10810729.
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Org Lett. 2000 May 04;2(9):1287-90. doi: 10.1021/ol0057277.

Sulfur-containing palladacycles as catalyst precursors for the Heck reaction.

Organic letters

Gruber, Zim, Ebeling, Monteiro, Dupont

Affiliations

  1. Laboratory of Molecular Catalysis, Instituto de Quimica, UFRGS, RS, Brazil.

PMID: 10810729 DOI: 10.1021/ol0057277

Abstract

[formula: see text] The air, water, and highly thermally stable sulfur-containing palladacycles, mainly derived from the ortho-palladation of benzylic thioethers, are exceptional catalyst precursors for the Heck reaction. The reaction can be performed with aryl lodides, bromides, and chlorides, with acrylic esters and styrene, leading to turnover numbers up to 1,850,000.

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