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Cotton FA, Murillo CA, Zhou HC. Oxidative scission of a Mo-Mo quadruple bond. Inorg Chem. 2000;39(15):3261-4doi: 10.1021/ic000092t.
Cotton, F. A., Murillo, C. A., & Zhou, H. C. (2000). Oxidative scission of a Mo-Mo quadruple bond. Inorganic chemistry, 39(15), 3261-4. https://doi.org/10.1021/ic000092t
Cotton, F A, et al. "Oxidative scission of a Mo-Mo quadruple bond." Inorganic chemistry vol. 39,15 (2000): 3261-4. doi: https://doi.org/10.1021/ic000092t
Cotton FA, Murillo CA, Zhou HC. Oxidative scission of a Mo-Mo quadruple bond. Inorg Chem. 2000 Jul 24;39(15):3261-4. doi: 10.1021/ic000092t. PMID: 11196863.
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Inorg Chem. 2000 Jul 24;39(15):3261-4. doi: 10.1021/ic000092t.

Oxidative scission of a Mo-Mo quadruple bond.

Inorganic chemistry

F A Cotton, C A Murillo, H C Zhou

Affiliations

  1. Laboratory for Molecular Structure and Bonding, Department of Chemistry, P.O. Box 30012, Texas A&M University, College Station, Texas 77842-3012, USA.

PMID: 11196863 DOI: 10.1021/ic000092t

Abstract

Two compounds containing the cations Mo2(DPhIP)4n+, n = 1 or 2 and DPhIP = the anion of 2,6-diphenyliminopiperidine, have been obtained by oxidation of the quadruply-bonded Mo2(DPhIP)4 species. The first oxidation process conserves the structure but results in a slight increase of the Mo-Mo distance from 2.114(1) to 2.136(2) A in [Mo2(DPhIP)4](PF6).2CH2Cl2 (1.2CH2Cl2). However, the second oxidation process breaks the dimolybdenum bond, giving a bioctahedral complex, [Mo2(DPhIP)4](BF4)2.5CH3CN.Et2O (2.5CH3CN.Et2O), with Mo...Mo separation of 2.9954(7) A. Crystallographic data for 1.2CH2Cl2 are space group C2/c, a = 17.1891(9) A, b = 17.807(1) A, c = 24.210(2) A, beta = 106.403(4) degrees, Z = 4; for 2.5CH3CN.Et2O, space group P2(1)/n, a = 16.523(5) A, b = 27.418(5) A, c = 18.163(3) A, beta = 93.48(2) degrees, Z = 4.

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