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Groarke M, McKervey MA, Miel H, et al. Nonracemic 2-diazo-1-oxiranyl-ethanone, a versatile chiral epoxide educt in diazocarbonyl reactions. Org Lett. 2000;2(16):2393-5doi: 10.1021/ol000034b.
Groarke, M., McKervey, M. A., Miel, H., & Nieuwenhuyzen, M. (2000). Nonracemic 2-diazo-1-oxiranyl-ethanone, a versatile chiral epoxide educt in diazocarbonyl reactions. Organic letters, 2(16), 2393-5. https://doi.org/10.1021/ol000034b
Groarke, et al. "Nonracemic 2-diazo-1-oxiranyl-ethanone, a versatile chiral epoxide educt in diazocarbonyl reactions." Organic letters vol. 2,16 (2000): 2393-5. doi: https://doi.org/10.1021/ol000034b
Groarke M, McKervey MA, Miel H, Nieuwenhuyzen M. Nonracemic 2-diazo-1-oxiranyl-ethanone, a versatile chiral epoxide educt in diazocarbonyl reactions. Org Lett. 2000 Aug 10;2(16):2393-5. doi: 10.1021/ol000034b. PMID: 10956504.
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Org Lett. 2000 Aug 10;2(16):2393-5. doi: 10.1021/ol000034b.

Nonracemic 2-diazo-1-oxiranyl-ethanone, a versatile chiral epoxide educt in diazocarbonyl reactions.

Organic letters

Groarke, McKervey, Miel, Nieuwenhuyzen

Affiliations

  1. School of Chemistry, The Queen's University, Belfast BT9 5AG, Northern Ireland.

PMID: 10956504 DOI: 10.1021/ol000034b

Abstract

(S)-(-)-2-Diazo-1-oxiranyl-ethanone, prepared in two steps from (R)-(+)-glycidol, has been employed as an intermediate in several characteristic diazocarbonyl reactions to yield novel, nonracemic products including an epoxy quinoxaline and epoxy thiazoles and oxazoles.

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