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Segura JL, Priego EM, Martin N, et al. A new photoactive and highly soluble C(60)-TTF-C(60) dimer: charge separation and recombination. Org Lett. 2000;2(25):4021-4doi: 10.1021/ol006645l.
Segura, J. L., Priego, E. M., Martin, N., Luo, C., & Guldi, D. M. (2000). A new photoactive and highly soluble C(60)-TTF-C(60) dimer: charge separation and recombination. Organic letters, 2(25), 4021-4. https://doi.org/10.1021/ol006645l
Segura, et al. "A new photoactive and highly soluble C(60)-TTF-C(60) dimer: charge separation and recombination." Organic letters vol. 2,25 (2000): 4021-4. doi: https://doi.org/10.1021/ol006645l
Segura JL, Priego EM, Martin N, Luo C, Guldi DM. A new photoactive and highly soluble C(60)-TTF-C(60) dimer: charge separation and recombination. Org Lett. 2000 Dec 14;2(25):4021-4. doi: 10.1021/ol006645l. PMID: 11112633.
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Org Lett. 2000 Dec 14;2(25):4021-4. doi: 10.1021/ol006645l.

A new photoactive and highly soluble C(60)-TTF-C(60) dimer: charge separation and recombination.

Organic letters

Segura, Priego, Martin, Luo, Guldi

Affiliations

  1. Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense, E-28040-Madrid, Spain, and Radiation Labotatory, University of Notre Dame, Notre Dame, Indiana 46556, USA.

PMID: 11112633 DOI: 10.1021/ol006645l

Abstract

The covalent linkage of two [60]fullerene cores to a tetrathiafulvalene (TTF) donor affords a soluble and photoactive C(60)-TTF-C(60) triad. Spectroscopic and photophysical characterization of the C(60)-TTF-C(60) triad are given. Although the cyclic voltammetry measurements reveal no notable interaction between the chromophores in the ground state, photophysical data show that in the excited state an intramolecular electron transfer, evolving from the TTF donor to the singlet state of C(60), prevails, yielding a long-lived charge separated radical pair.

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