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Zim D, Gruber AS, Ebeling G, et al. Sulfur-containing palladacycles: efficient phosphine-free catalyst precursors for the Suzuki cross-coupling reaction at room temperature. Org Lett. 2000;2(18):2881-4doi: 10.1021/ol0063048.
Zim, D., Gruber, A. S., Ebeling, G., Dupont, J., & Monteiro, A. L. (2000). Sulfur-containing palladacycles: efficient phosphine-free catalyst precursors for the Suzuki cross-coupling reaction at room temperature. Organic letters, 2(18), 2881-4. https://doi.org/10.1021/ol0063048
Zim, D, et al. "Sulfur-containing palladacycles: efficient phosphine-free catalyst precursors for the Suzuki cross-coupling reaction at room temperature." Organic letters vol. 2,18 (2000): 2881-4. doi: https://doi.org/10.1021/ol0063048
Zim D, Gruber AS, Ebeling G, Dupont J, Monteiro AL. Sulfur-containing palladacycles: efficient phosphine-free catalyst precursors for the Suzuki cross-coupling reaction at room temperature. Org Lett. 2000 Sep 07;2(18):2881-4. doi: 10.1021/ol0063048. PMID: 10964389.
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Org Lett. 2000 Sep 07;2(18):2881-4. doi: 10.1021/ol0063048.

Sulfur-containing palladacycles: efficient phosphine-free catalyst precursors for the Suzuki cross-coupling reaction at room temperature.

Organic letters

D Zim, A S Gruber, G Ebeling, J Dupont, A L Monteiro

Affiliations

  1. Laboratory of Molecular Catalysis, Instituto de Química, UFRGS, Av. Bento Gonçalves, 9500 Porto Alegre, RS 91501-970, Brazil.

PMID: 10964389 DOI: 10.1021/ol0063048

Abstract

[reaction: see text] Cyclopalladated compounds derived from the ortho-metalation of benzylic tert-butyl thioethers are excellent catalyst precursors for the Suzuki cross-coupling reaction of aryl bromides and chlorides with phenylboronic acid under mild reaction conditions. A broad range of substrates and functional groups are tolerated in this protocol, and highly catalytic activity is attained.

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