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Magdziak D, Pettus LH, Pettus TR. Enantioselective hydride abstraction in organic substrates: a novel use for chiral carbenium ions. Org Lett. 2001;3(4):557-9doi: 10.1021/ol006963k.
Magdziak, D., Pettus, L. H., & Pettus, T. R. (2001). Enantioselective hydride abstraction in organic substrates: a novel use for chiral carbenium ions. Organic letters, 3(4), 557-9. https://doi.org/10.1021/ol006963k
Magdziak, D, et al. "Enantioselective hydride abstraction in organic substrates: a novel use for chiral carbenium ions." Organic letters vol. 3,4 (2001): 557-9. doi: https://doi.org/10.1021/ol006963k
Magdziak D, Pettus LH, Pettus TR. Enantioselective hydride abstraction in organic substrates: a novel use for chiral carbenium ions. Org Lett. 2001 Feb 22;3(4):557-9. doi: 10.1021/ol006963k. PMID: 11178824.
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Org Lett. 2001 Feb 22;3(4):557-9. doi: 10.1021/ol006963k.

Enantioselective hydride abstraction in organic substrates: a novel use for chiral carbenium ions.

Organic letters

D Magdziak, L H Pettus, T R Pettus

Affiliations

  1. Department of Chemistry and Biochemistry, University of California at Santa Barbara, 93106, USA.

PMID: 11178824 DOI: 10.1021/ol006963k

Abstract

[reaction: see text] It is surprising that chiral cations have not been used to distinguish between prochiral hydrides when converse notions, such as asymmetric addition of a hyride to a prochiral functional group or use of a chiral anion to distinguish between a pair of prochiral protons, are methods employed everyday in enantioselective synthesis. To the best of our knowledge, this Letter describes the first example of an oxidative enantioselective hydride transfer process.

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