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Grintselev-Knyazev GV, Lyssenko KA, Antipin MY, et al. Two isostructural carboranes: 3-phenyl-1,2-dicarba-closo-dodecaborane(12) and 1-phenyl-1,7-dicarba-closo-dodecaborane(12). Acta Crystallogr C. 2001;57:827-9doi: 10.1107/s0108270101005455.
Grintselev-Knyazev, G. V., Lyssenko, K. A., Antipin, M. Y., Knyazev, S. P., Kirin, V. N., & Chernyshev, E. A. (2001). Two isostructural carboranes: 3-phenyl-1,2-dicarba-closo-dodecaborane(12) and 1-phenyl-1,7-dicarba-closo-dodecaborane(12). Acta crystallographica. Section C, Crystal structure communications, 57827-9. https://doi.org/10.1107/s0108270101005455
Grintselev-Knyazev, G V, et al. "Two isostructural carboranes: 3-phenyl-1,2-dicarba-closo-dodecaborane(12) and 1-phenyl-1,7-dicarba-closo-dodecaborane(12)." Acta crystallographica. Section C, Crystal structure communications vol. 57 (2001): 827-9. doi: https://doi.org/10.1107/s0108270101005455
Grintselev-Knyazev GV, Lyssenko KA, Antipin MY, Knyazev SP, Kirin VN, Chernyshev EA. Two isostructural carboranes: 3-phenyl-1,2-dicarba-closo-dodecaborane(12) and 1-phenyl-1,7-dicarba-closo-dodecaborane(12). Acta Crystallogr C. 2001 Jul;57:827-9. doi: 10.1107/s0108270101005455. Epub 2001 Jul 09. PMID: 11443255.
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Acta Crystallogr C. 2001 Jul;57:827-9. doi: 10.1107/s0108270101005455. Epub 2001 Jul 09.

Two isostructural carboranes: 3-phenyl-1,2-dicarba-closo-dodecaborane(12) and 1-phenyl-1,7-dicarba-closo-dodecaborane(12).

Acta crystallographica. Section C, Crystal structure communications

G V Grintselev-Knyazev, K A Lyssenko, M Y Antipin, S P Knyazev, V N Kirin, E A Chernyshev

Affiliations

  1. X-Ray Structural Centre, Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, B-334, Moscow 117813, Russian Federation. [email protected]

PMID: 11443255 DOI: 10.1107/s0108270101005455

Abstract

Two phenyl-substituted carboranes, 3-phenyl-1,2-dicarba-closo-dodecaborane(12), C8H16B10, (I), and 1-phenyl-1,7-dicarba-closo-dodecaborane(12), C8H16B10, (II), were found to be isostructural. Comparison of the bond angles at the ipso-C atoms of the phenyl substituent for (I) and (II) [117.71 (3) and 118.45 (10) degrees, respectively] indicates that electron donation of the carborane cage for B- and C-substituted carboranes is different.

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