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Org Lett. 2001 Jan 11;3(1):131-4. doi: 10.1021/ol0068501.

Novel synthesis of electroresponsive poly(thiophenylene) through a Michael-type addition.

Organic letters

K Yamamoto, M Higuchi, H Takai, T Nishiumi

Affiliations

  1. Department of Chemistry, Faculty of Science & Technology, Keio University, Yokohama, 223-8522 Japan. [email protected]

PMID: 11429856 DOI: 10.1021/ol0068501

Abstract

[figure: see text] A novel poly(thiophenylene) having N,N-diphenyl-1,4-phenylenediamine (PDA) as a redox unit was synthesized through a Michael-type addition. This polymerization proceeded at room temperature without catalysts. The polymer obtained acted as a good electroresponsive material with moderate thermostability.

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