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Gray SD, Thorman JL, Adamian VA, et al. Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(eta(2)-PhN=NPh). Inorg Chem. 1998;37(1):1-4doi: 10.1021/ic970952e.
Gray, S. D., Thorman, J. L., Adamian, V. A., Kadish, K. M., & Woo, L. K. (1998). Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(eta(2)-PhN=NPh). Inorganic chemistry, 37(1), 1-4. https://doi.org/10.1021/ic970952e
Gray, Steven D., et al. "Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(eta(2)-PhN=NPh)." Inorganic chemistry vol. 37,1 (1998): 1-4. doi: https://doi.org/10.1021/ic970952e
Gray SD, Thorman JL, Adamian VA, Kadish KM, Woo LK. Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(eta(2)-PhN=NPh). Inorg Chem. 1998 Jan 12;37(1):1-4. doi: 10.1021/ic970952e. PMID: 11670252.
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Inorg Chem. 1998 Jan 12;37(1):1-4. doi: 10.1021/ic970952e.

Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(eta(2)-PhN=NPh).

Inorganic chemistry

Steven D. Gray, Joseph L. Thorman, Victor A. Adamian, Karl M. Kadish, L. Keith Woo

Affiliations

  1. Departments of Chemistry, Iowa State University, Ames, Iowa 50011-3111, and University of Houston, Houston, Texas 77204.

PMID: 11670252 DOI: 10.1021/ic970952e

Abstract

Treatment of (TTP)Ti(eta(2)-RC&tbd1;CR) (R = Et or Ph) with PhN=NPh results in formation of the azobenzene adduct (TTP)Ti(eta(2)-PhN=NPh) (1) in good isolated yield. Complex 1 reacts with (TTP)Ti(eta(2)-RC&tbd1;CR) at elevated temperatures to cleanly afford 2 equiv of the phenylimido compound, (TTP)Ti=NPh (2). The azobenzene complex, 1, is also formed in low yields by the reaction of the (TTP)Ti=NPh (2) with excess 1,2-diphenylhydrazine. The electrochemistry of the azobenzene adduct (1) and the phenylimido complex (2) is investigated by cyclic voltammetry experiments.

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