Display options
Cite
Koffi-Sokpa EI, Calfee DT, Allred BR, et al. Activation of Ligand Reactivity: Thiolate C-S and Dithiophosphate Ester C-O Heterolyses within a Dimolybdenum(V) System. Inorg Chem. 1999;38(4):802-813doi: 10.1021/ic981303l.
Koffi-Sokpa, E. I., Calfee, D. T., Allred, B. R., Davis, J. L., Haub, E. K., Rich, A. K., Porter, R. A., Mashuta, M. S., Richardson, J. F., & Noble, M. E. (1999). Activation of Ligand Reactivity: Thiolate C-S and Dithiophosphate Ester C-O Heterolyses within a Dimolybdenum(V) System. Inorganic chemistry, 38(4), 802-813. https://doi.org/10.1021/ic981303l
Koffi-Sokpa, Edith I., et al. "Activation of Ligand Reactivity: Thiolate C-S and Dithiophosphate Ester C-O Heterolyses within a Dimolybdenum(V) System." Inorganic chemistry vol. 38,4 (1999): 802-813. doi: https://doi.org/10.1021/ic981303l
Koffi-Sokpa EI, Calfee DT, Allred BR, Davis JL, Haub EK, Rich AK, Porter RA, Mashuta MS, Richardson JF, Noble ME. Activation of Ligand Reactivity: Thiolate C-S and Dithiophosphate Ester C-O Heterolyses within a Dimolybdenum(V) System. Inorg Chem. 1999 Feb 22;38(4):802-813. doi: 10.1021/ic981303l. PMID: 11670847.
Copy Download .nbib Format: NLM
Share it on

Inorg Chem. 1999 Feb 22;38(4):802-813. doi: 10.1021/ic981303l.

Activation of Ligand Reactivity: Thiolate C-S and Dithiophosphate Ester C-O Heterolyses within a Dimolybdenum(V) System.

Inorganic chemistry

Edith I. Koffi-Sokpa, D. Troy Calfee, Brian R. T. Allred, Jackie L. Davis, Elaine K. Haub, Alexis K. Rich, Richard A. Porter, Mark S. Mashuta, John F. Richardson, Mark E. Noble

Affiliations

  1. Department of Chemistry, University of Louisville, Louisville, Kentucky 40292.

PMID: 11670847 DOI: 10.1021/ic981303l

Abstract

Ligand reactivity was demonstrated for sulfide alkylation, thiolate dealkylation, and dithiophosphate de-esterification within molybdenum(V) dimers. The cationic complex [Mo(2)(NC(6)H(4)Me)(2)(S(2)P(OEt)(2))(2)(&mgr;-O(2)CMe)(&mgr;-SR)(2)](+) was inductively activated toward thiolate C-S and dithiophosphate C-O heterolyses. The dealkylations were studied using anionic nucleophiles, and various reactivity patterns were characterized. The de-esterification of the diethyl dithiophosphate ligands produced complexes containing the rare monoester EtO(O)PS(2)(2)(-) ligand. This ligand's phosphoryl group was poorly nucleophilic but weakly basic. Crystallographic comparisons between the activated cation and the neutral complex [Mo(2)(NC(6)H(4)Me)(2)(S(2)P(OEt)(2))(2)(&mgr;-O(2)CMe)(&mgr;-S)(&mgr;-SMe)] were conducted to delineate structural differences related to the activation. A crystallographic study was also done of the complex [Mo(2)(NC(6)H(4)CH(3))(2)(S(2)P(OEt)(2))(S(2)P(O)OEt)(&mgr;-O(2)CMe)(&mgr;-SEt)(2)], which provided internal comparison of monoester EtO(O)PS(2)(2)(-) and diester (EtO)(2)PS(2)(-) ligand types.

Publication Types