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Zim D, Lando VR, Dupont J, et al. NiCl(2)(PCy(3))(2): a simple and efficient catalyst precursor for the Suzuki cross-coupling of aryl tosylates and arylboronic acids. Org Lett. 2001;3(19):3049-51doi: 10.1021/ol016526l.
Zim, D., Lando, V. R., Dupont, J., & Monteiro, A. L. (2001). NiCl(2)(PCy(3))(2): a simple and efficient catalyst precursor for the Suzuki cross-coupling of aryl tosylates and arylboronic acids. Organic letters, 3(19), 3049-51. https://doi.org/10.1021/ol016526l
Zim, D, et al. "NiCl(2)(PCy(3))(2): a simple and efficient catalyst precursor for the Suzuki cross-coupling of aryl tosylates and arylboronic acids." Organic letters vol. 3,19 (2001): 3049-51. doi: https://doi.org/10.1021/ol016526l
Zim D, Lando VR, Dupont J, Monteiro AL. NiCl(2)(PCy(3))(2): a simple and efficient catalyst precursor for the Suzuki cross-coupling of aryl tosylates and arylboronic acids. Org Lett. 2001 Sep 20;3(19):3049-51. doi: 10.1021/ol016526l. PMID: 11554840.
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Org Lett. 2001 Sep 20;3(19):3049-51. doi: 10.1021/ol016526l.

NiCl(2)(PCy(3))(2): a simple and efficient catalyst precursor for the Suzuki cross-coupling of aryl tosylates and arylboronic acids.

Organic letters

D Zim, V R Lando, J Dupont, A L Monteiro

Affiliations

  1. Laboratory of Molecular Catalysis, Instituto de Química, UFRGS, Av. Bento Gonçalves 9500, Porto Alegre 91501-970, CP 15003, RS, Brazil.

PMID: 11554840 DOI: 10.1021/ol016526l

Abstract

NiCl(2)(PCy(3))(2) associated with PCy(3) promotes the selective cross-coupling of aryltosylates with arylboronic acids under relatively mild reaction conditions, and a variety of functional groups are tolerated in both arenes. This is one of the simplest and most efficient experimental procedures for the coupling of arylboronic acids with aryl tosylates reported to date. Reaction: see text.

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