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Rondeau D, Kreher D, Cariou M, et al. Electrolytic electrospray ionization mass spectrometry of C(60)-TTF-C(60) derivatives: high-resolution mass measurement and molecular ion gas-phase reactivity. Rapid Commun Mass Spectrom. 2001;15(18):1708-12doi: 10.1002/rcm.423.
Rondeau, D., Kreher, D., Cariou, M., Hudhomme, P., Gorgues, A., & Richomme, P. (2001). Electrolytic electrospray ionization mass spectrometry of C(60)-TTF-C(60) derivatives: high-resolution mass measurement and molecular ion gas-phase reactivity. Rapid communications in mass spectrometry : RCM, 15(18), 1708-12. https://doi.org/10.1002/rcm.423
Rondeau, D, et al. "Electrolytic electrospray ionization mass spectrometry of C(60)-TTF-C(60) derivatives: high-resolution mass measurement and molecular ion gas-phase reactivity." Rapid communications in mass spectrometry : RCM vol. 15,18 (2001): 1708-12. doi: https://doi.org/10.1002/rcm.423
Rondeau D, Kreher D, Cariou M, Hudhomme P, Gorgues A, Richomme P. Electrolytic electrospray ionization mass spectrometry of C(60)-TTF-C(60) derivatives: high-resolution mass measurement and molecular ion gas-phase reactivity. Rapid Commun Mass Spectrom. 2001;15(18):1708-12. doi: 10.1002/rcm.423. PMID: 11555870.
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Rapid Commun Mass Spectrom. 2001;15(18):1708-12. doi: 10.1002/rcm.423.

Electrolytic electrospray ionization mass spectrometry of C(60)-TTF-C(60) derivatives: high-resolution mass measurement and molecular ion gas-phase reactivity.

Rapid communications in mass spectrometry : RCM

D Rondeau, D Kreher, M Cariou, P Hudhomme, A Gorgues, P Richomme

Affiliations

  1. Service Commun d'Analyses Spectroscopiques, Université d'Angers, 2 Bd Lavoisier, 49045 Angers Cedex, France. [email protected]

PMID: 11555870 DOI: 10.1002/rcm.423

Abstract

The electrochemical process involved in electrospray ionization is used to obtain odd-electron molecular ions from C(60)-TTF-C(60) and its methano derivatives. Exact mass measurements obtained using high-resolution mass spectrometry are reported, and the gas-phase behavior of the radical cation (retro-Diels-Alder reaction and [M/2 + H](+) ion formation) is described.

Copyright 2001 John Wiley & Sons, Ltd.

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