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Acta Crystallogr A. 2001 Sep;57:482-91. doi: 10.1107/s0108767301005098. Epub 2001 Sep 01.

Analysis of chord-length distributions.

Acta crystallographica. Section A, Foundations of crystallography

C Burger, W Ruland

Affiliations

  1. Max-Planck-Institut für Kolloid- und Grenzflächenforschung, D-14424 Potsdam, Germany. [email protected]

PMID: 11526297 DOI: 10.1107/s0108767301005098

Abstract

A closed-form analytical solution for the inversion of the integral equation relating small-angle scattering intensity distributions of two-phase systems to chord-length distributions is presented. The result is generalized to arbitrary derivatives of higher order of the autocorrelation function and to arbitrary projections of the scattering intensity (including slit collimation). This inverse transformation offers an elegant way to investigate the impact of certain features, e.g. singularities, in the chord-length distribution or its higher-order derivatives on the scattering curve, e.g. oscillatory components in the asymptotic behavior at a large scattering vector. Several examples are discussed.

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