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Nestler O, Severin K. A ruthenium porphyrin catalyst immobilized in a highly cross-linked polymer. Org Lett. 2001;3(24):3907-9doi: 10.1021/ol016754f.
Nestler, O., & Severin, K. (2001). A ruthenium porphyrin catalyst immobilized in a highly cross-linked polymer. Organic letters, 3(24), 3907-9. https://doi.org/10.1021/ol016754f
Nestler, O, and Severin, K. "A ruthenium porphyrin catalyst immobilized in a highly cross-linked polymer." Organic letters vol. 3,24 (2001): 3907-9. doi: https://doi.org/10.1021/ol016754f
Nestler O, Severin K. A ruthenium porphyrin catalyst immobilized in a highly cross-linked polymer. Org Lett. 2001 Nov 29;3(24):3907-9. doi: 10.1021/ol016754f. PMID: 11720566.
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Org Lett. 2001 Nov 29;3(24):3907-9. doi: 10.1021/ol016754f.

A ruthenium porphyrin catalyst immobilized in a highly cross-linked polymer.

Organic letters

O Nestler, K Severin

Affiliations

  1. Institut de Chimie Minérale et Analytique, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland.

PMID: 11720566 DOI: 10.1021/ol016754f

Abstract

An immobilized Ru(meso-tetraarylporphyrin) complex was shown to be a very efficient catalyst for the epoxidation of olefins. In the presence of HBr, alcohols and even alkanes could be converted to the corresponding ketones. For the latter reactions the polymeric catalyst displayed a significantly enhanced activity when compared to that of the homogeneous version.[reaction: see text]

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