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Esquius G, Pons J, Yáñez R, et al. Bis[mu-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa2N1:N2]bis[(eta4-1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate. Acta Crystallogr C. 2002;58:m133-4doi: 10.1107/s0108270101020017.
Esquius, G., Pons, J., Yáñez, R., Ros, J., Solans, X., & Font-Bardia, M. (2002). Bis[mu-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa2N1:N2]bis[(eta4-1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate. Acta crystallographica. Section C, Crystal structure communications, 58m133-4. https://doi.org/10.1107/s0108270101020017
Esquius, Glòria, et al. "Bis[mu-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa2N1:N2]bis[(eta4-1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate." Acta crystallographica. Section C, Crystal structure communications vol. 58 (2002): m133-4. doi: https://doi.org/10.1107/s0108270101020017
Esquius G, Pons J, Yáñez R, Ros J, Solans X, Font-Bardia M. Bis[mu-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa2N1:N2]bis[(eta4-1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate. Acta Crystallogr C. 2002 Feb;58:m133-4. doi: 10.1107/s0108270101020017. Epub 2002 Jan 31. PMID: 11828104.
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Acta Crystallogr C. 2002 Feb;58:m133-4. doi: 10.1107/s0108270101020017. Epub 2002 Jan 31.

Bis[mu-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa2N1:N2]bis[(eta4-1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate.

Acta crystallographica. Section C, Crystal structure communications

Glòria Esquius, Josefina Pons, Ramón Yáñez, Josep Ros, Xavier Solans, Mercè Font-Bardia

Affiliations

  1. Departament de Química, Universitat Autònoma de Barcelona, E-08193 Bellaterra, Spain.

PMID: 11828104 DOI: 10.1107/s0108270101020017

Abstract

In the title compound, [Rh(2)(C(8)H(15)N(3))(2)(C(8)H(12))(2)]Cl(2).CH(2)Cl(2).CH(3)OH, the dinuclear Rh(I) complex has C(2) symmetry and the two pyrazolato ligands act as mu-bridges. The coordination of each Rh(I) cation is completed by one cyclooctadiene (COD) ligand. It is shown that the average Rh-C(COD) distance is linearly dependent on the Rh-N(pyrazole) distance in this type of compound, and this is ascribed to the steric hindrance produced by the packing.

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