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Horley GA, Mahon MF, Molloy KC, et al. Structures of Sb(OC(6)H(3)Me(2)-2,6)(3) and Sb(OEt)(5) x NH(3): the first authenticated monomeric Sb(OR)(n) (n = 3, 5). Inorg Chem. 2002;41(6):1652-7doi: 10.1021/ic0106726.
Horley, G. A., Mahon, M. F., Molloy, K. C., Venter, M. M., Haycock, P. W., & Myers, C. P. (2002). Structures of Sb(OC(6)H(3)Me(2)-2,6)(3) and Sb(OEt)(5) x NH(3): the first authenticated monomeric Sb(OR)(n) (n = 3, 5). Inorganic chemistry, 41(6), 1652-7. https://doi.org/10.1021/ic0106726
Horley, Graeme A, et al. "Structures of Sb(OC(6)H(3)Me(2)-2,6)(3) and Sb(OEt)(5) x NH(3): the first authenticated monomeric Sb(OR)(n) (n = 3, 5)." Inorganic chemistry vol. 41,6 (2002): 1652-7. doi: https://doi.org/10.1021/ic0106726
Horley GA, Mahon MF, Molloy KC, Venter MM, Haycock PW, Myers CP. Structures of Sb(OC(6)H(3)Me(2)-2,6)(3) and Sb(OEt)(5) x NH(3): the first authenticated monomeric Sb(OR)(n) (n = 3, 5). Inorg Chem. 2002 Mar 25;41(6):1652-7. doi: 10.1021/ic0106726. PMID: 11896736.
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Inorg Chem. 2002 Mar 25;41(6):1652-7. doi: 10.1021/ic0106726.

Structures of Sb(OC(6)H(3)Me(2)-2,6)(3) and Sb(OEt)(5) x NH(3): the first authenticated monomeric Sb(OR)(n) (n = 3, 5).

Inorganic chemistry

Graeme A Horley, Mary F Mahon, Kieran C Molloy, Monica M Venter, Peter W Haycock, Christopher P Myers

Affiliations

  1. Birchall Centre for Inorganic Chemistry and Materials Science, School of Chemistry and Physics, Lennard-Jones Laboratories, Keele University, Staffordshire ST5 5BG, UK.

PMID: 11896736 DOI: 10.1021/ic0106726

Abstract

The first monomeric antimony alkoxides, Sb(OC(6)H(3)Me(2))(3) (1) and Sb(OEt)(5) x NH(3) (2), have been crystallographically characterized. The former adopts a trigonal pyramidal geometry, while the latter is octahedral about antimony; hydrogen bonding between NH(3) and SbOEt groups in Sb(OEt)(5) small middle dotNH(3) creates a one-dimensional lattice arrangement. Reaction of pyridine with SbCl(5) in EtOH/hexane yields the salt [Hpy(+)](9)[Sb(2)Cl(11)(5)(-)][Cl(-)](4) (3), which has also been crystallographically characterized. Crystallographic data: 1, C(24)H(27)O(3)Sb, a = 10.9080(2), b = 11.9660(2), c = 17.7260(4) A, alpha = 109.740(1) degrees, monoclinic P2(1)/c (unique axis a), Z = 4; 2, C(10)H(28)NO(5)Sb, a = 7.7220(1), b = 19.0700(2), c = 21.6800(3) A, beta = 93.4960(7) degrees, monoclinic P2(1)/c, Z = 8; 3, C(45)H(54)Cl(15)N(9)Sb(2), a = 13.4300(2), b = 14.4180(2), c = 17.4180(3) A, alpha = 82.7650(7), beta = 77.5570(7), gamma = 70.7670(7) degrees, triclinic P1, Z = 2.

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