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Iranpoor N, Firouzabadi H, Shaterian HR. A new approach to the reduction of sulfoxides to sulfides with 1,3-dithiane in the presence of electrophilic bromine as catalyst. J Org Chem. 2002;67(9):2826-30doi: 10.1021/jo016027y.
Iranpoor, N., Firouzabadi, H., & Shaterian, H. R. (2002). A new approach to the reduction of sulfoxides to sulfides with 1,3-dithiane in the presence of electrophilic bromine as catalyst. The Journal of organic chemistry, 67(9), 2826-30. https://doi.org/10.1021/jo016027y
Iranpoor, Nasser, et al. "A new approach to the reduction of sulfoxides to sulfides with 1,3-dithiane in the presence of electrophilic bromine as catalyst." The Journal of organic chemistry vol. 67,9 (2002): 2826-30. doi: https://doi.org/10.1021/jo016027y
Iranpoor N, Firouzabadi H, Shaterian HR. A new approach to the reduction of sulfoxides to sulfides with 1,3-dithiane in the presence of electrophilic bromine as catalyst. J Org Chem. 2002 May 03;67(9):2826-30. doi: 10.1021/jo016027y. PMID: 11975533.
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J Org Chem. 2002 May 03;67(9):2826-30. doi: 10.1021/jo016027y.

A new approach to the reduction of sulfoxides to sulfides with 1,3-dithiane in the presence of electrophilic bromine as catalyst.

The Journal of organic chemistry

Nasser Iranpoor, Habib Firouzabadi, Hamid Reza Shaterian

Affiliations

  1. Department of Chemistry, Shiraz University, Shiraz 71454, Iran. [email protected]

PMID: 11975533 DOI: 10.1021/jo016027y

Abstract

A new, mild, and novel method is described for the efficient deoxygenation of sulfoxides to their corresponding sulfides with 1,3-dithiane at room temperature in the presence of catalytic amounts of N-bromosuccinimide (NBS), 2,4,4,6-tetrabromo-2,5-cyclohexadienone (TABCO), or Br(2) as the source of electrophilic bromine.

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