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Phillips AD, Wright RJ, Olmstead MM, et al. Synthesis and characterization of 2,6-Dipp(2)-H(3)C(6)SnSnC(6)H(3)-2,6-Dipp(2) (Dipp = C(6)H(3)-2,6-Pr(i)(2)): a tin analogue of an alkyne. J Am Chem Soc. 2002;124(21):5930-1doi: 10.1021/ja0257164.
Phillips, A. D., Wright, R. J., Olmstead, M. M., & Power, P. P. (2002). Synthesis and characterization of 2,6-Dipp(2)-H(3)C(6)SnSnC(6)H(3)-2,6-Dipp(2) (Dipp = C(6)H(3)-2,6-Pr(i)(2)): a tin analogue of an alkyne. Journal of the American Chemical Society, 124(21), 5930-1. https://doi.org/10.1021/ja0257164
Phillips, Andrew D, et al. "Synthesis and characterization of 2,6-Dipp(2)-H(3)C(6)SnSnC(6)H(3)-2,6-Dipp(2) (Dipp = C(6)H(3)-2,6-Pr(i)(2)): a tin analogue of an alkyne." Journal of the American Chemical Society vol. 124,21 (2002): 5930-1. doi: https://doi.org/10.1021/ja0257164
Phillips AD, Wright RJ, Olmstead MM, Power PP. Synthesis and characterization of 2,6-Dipp(2)-H(3)C(6)SnSnC(6)H(3)-2,6-Dipp(2) (Dipp = C(6)H(3)-2,6-Pr(i)(2)): a tin analogue of an alkyne. J Am Chem Soc. 2002 May 29;124(21):5930-1. doi: 10.1021/ja0257164. PMID: 12022812.
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J Am Chem Soc. 2002 May 29;124(21):5930-1. doi: 10.1021/ja0257164.

Synthesis and characterization of 2,6-Dipp(2)-H(3)C(6)SnSnC(6)H(3)-2,6-Dipp(2) (Dipp = C(6)H(3)-2,6-Pr(i)(2)): a tin analogue of an alkyne.

Journal of the American Chemical Society

Andrew D Phillips, Robert J Wright, Marilyn M Olmstead, Philip P Power

Affiliations

  1. Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California 95616, USA.

PMID: 12022812 DOI: 10.1021/ja0257164

Abstract

The reaction of Sn(Cl)C(6)H(3)-2,6-Dipp(2) (Dipp = C(6)H(3)-2,6-Pr(i)()(2)) with a stoichiometric amount of potassium in benzene affords 2,6-Pr(i)()(2)-H(3)C(6)SnSnC(6)H(3)-2,6-Pr(i)()(2) (1) as dark blue-green crystals. The compound 1 is a tin analogue of an alkyne. It was characterized by (1)H and (13)C NMR and UV-vis spectroscopy, cyclic voltammetry, combustion analysis and X-ray crystallography. The structural data show that 1 has a trans-bent, planar C(ipso)SnSnC(ipso) skeleton with a Sn-Sn bond distance of 2.6675(4) A and a Sn-Sn-C angle of 125.24(7) degrees. The Sn-Sn distance, which is ca. 0.15 A shorter than a conventional Sn-Sn single bond, and the trans-bent structure indicate the presence Sn-Sn multiple bond character unlike the related singly bonded ArPbPbAr species.

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