Acta Crystallogr C. 2002 Jun;58:O370-2. doi: 10.1107/s0108270102007722. Epub 2002 May 31.
A neutral complex of an azino[bond]DTDAF compound with TCNQ.
Acta crystallographica. Section C, Crystal structure communications
Renata Toplak, Dominique Lorcy
Affiliations
Affiliations
- Synthèse et Electrosynthèse Organiques, UMR CNRS 6510, Université de Rennes 1, 35042 Rennes Cedex, France.
PMID: 12050446
DOI: 10.1107/s0108270102007722
Abstract
In the crystal structure of the title 1:1 complex, ethyl 2-[[5-(ethoxycarbonyl)-2,3-dihydro-3,4-dimethyl-1,3-thiazol-2-ylidene]hydrazono]-2,3-dihydro-3,4-dimethyl-1,3-thiazole-5-carboxylate-7,7,8,8-tetracyano-p-quinodimethane (1/1), C(16)H(22)N(4)O(4)S(2) x C(12)H(4)N(4), the planar donor and tetracyano-p-quinodimethane (TCNQ) molecules are each located on inversion centres and are stacked alternately. The bond lengths indicate that, in this complex, the donor and acceptor are neutral, as confirmed by IR investigation.
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