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Karlsen T, Børve KJ, Saethre LJ, et al. Toward the spectrum of free polyethylene: linear alkanes studied by carbon 1s photoelectron spectroscopy and theory. J Am Chem Soc. 2002;124(26):7866-73doi: 10.1021/ja010649j.
Karlsen, T., Børve, K. J., Saethre, L. J., Wiesner, K., Bässler, M., & Svensson, S. (2002). Toward the spectrum of free polyethylene: linear alkanes studied by carbon 1s photoelectron spectroscopy and theory. Journal of the American Chemical Society, 124(26), 7866-73. https://doi.org/10.1021/ja010649j
Karlsen, Tor, et al. "Toward the spectrum of free polyethylene: linear alkanes studied by carbon 1s photoelectron spectroscopy and theory." Journal of the American Chemical Society vol. 124,26 (2002): 7866-73. doi: https://doi.org/10.1021/ja010649j
Karlsen T, Børve KJ, Saethre LJ, Wiesner K, Bässler M, Svensson S. Toward the spectrum of free polyethylene: linear alkanes studied by carbon 1s photoelectron spectroscopy and theory. J Am Chem Soc. 2002 Jul 03;124(26):7866-73. doi: 10.1021/ja010649j. PMID: 12083942.
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J Am Chem Soc. 2002 Jul 03;124(26):7866-73. doi: 10.1021/ja010649j.

Toward the spectrum of free polyethylene: linear alkanes studied by carbon 1s photoelectron spectroscopy and theory.

Journal of the American Chemical Society

Tor Karlsen, Knut J Børve, Leif J Saethre, Karoline Wiesner, Margit Bässler, Svante Svensson

Affiliations

  1. Department of Chemistry, University of Bergen, N-5007 Bergen, Norway. [email protected]

PMID: 12083942 DOI: 10.1021/ja010649j

Abstract

Trends in carbon 1s ionization energies for the linear alkanes have been investigated using third-generation synchrotron radiation. The study comprises CH(4), C(2)H(6), C(3)H(8), C(4)H(10), C(5)H(12), C(6)H(14), and C(8)H(18). Both inter- and intramolecular shifts in ionization energy have been determined from gas-phase spectra and ab initio calculations. The shifts are decomposed into initial-state and final-state contributions and are shown to relate to the fundamental chemical properties of group electronegativity and polarizability. By extrapolation, we predict C1s spectra of larger n-alkanes, converging toward isolated strands of polyethylene.

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