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Chem Commun (Camb). 2002 Feb 07;(3):236-7. doi: 10.1039/b108661h.

Ion-neutral complexes formation and 1,3-proton transfer in the chemical ionization of alkylcyclohexyl benzoates.

Chemical communications (Cambridge, England)

Chagit Denekamp, Amnon Stanger

Affiliations

  1. Department of Chemistry, Institute of Catalysis Science and Technology, Lise-Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel. [email protected]

PMID: 12120382 DOI: 10.1039/b108661h

Abstract

CI, CID, labelling experiments and DFT calculations are used for the elucidation of the mechanism for the decomposition of cyclohexyl benzoates, which proceeds through 1,3-H shift and two equilibrating ion-neutral complexes.

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