Acta Crystallogr C. 2002 Dec;58:m591-2. doi: 10.1107/s0108270102019509. Epub 2002 Nov 20.

catena-Poly[tris(ethylenediamine-kappa2N,N')nickel(II) [[trithiocyanato-kappa3N-sodium(I)]-mu-aqua-kappa2O:O]].

Acta crystallographica. Section C, Crystal structure communications

Liang Shen, Zhi Min Jing

PMID: 12466607 DOI: 10.1107/s0108270102019509

Abstract

The title complex, ([Ni(C(2)H(8)N(2))(3)][Na(NCS)(3)(H(2)O)])(n), consists of discrete [Ni(en)(3)](2+) dications (en is ethylenediamine) and polymeric [(H(2)O)(0.5)Na(NCS)(3)(H(2)O)(0.5)](n)(2n-) anions. The compound crystallizes in space group P-3c1. The Ni(II) atom lies on a threefold axis and has a distorted octahedral coordination geometry. The Na(+) cation also lies on a site with imposed crystallographic threefold symmetry and is coordinated by the thiocyanate N atoms (the thiocyanates are in general positions), by one water molecule with crystallographically imposed 32 symmetry and by a second water molecule with crystallographically imposed -3 symmetry. The unique Na atom thus has trigonal-bipyramidal coordination. The O atoms of the water molecules bridge the Na(+) cations to form one-dimensional polymeric chains in the crystal structure. The [Ni(en)(3)](2+) dications are distributed around and between the chains and are linked to them via N-H.S hydrogen bonds.

Publication Types

• Journal Article