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Chem Commun (Camb). 2001 Nov 21;(22):2372-3. doi: 10.1039/b108132b.

Preparation, structure and catalytic properties of a binuclear Pd(0) complex with bridging silylene ligands.

Chemical communications (Cambridge, England)

A Fürstner, H Krause, C W Lehmann

Affiliations

  1. Max-Planck-Institut für Kohlenforschung, D-45470 Mülheim/Ruhr, Germany. [email protected]

PMID: 12240081 DOI: 10.1039/b108132b

Abstract

In contrast to the N-heterocyclic carbene (NHC) 1, the homologous N-heterocyclic silylene (NHS) 4 acts as a bridging ligand to Pd(0), giving rise to the dinuclear complex 5 which is catalytically active in Suzuki reactions.

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