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Chem Commun (Camb). 2001 Nov 07;(21):2172-3. doi: 10.1039/b105231b.

Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterizations of [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane).

Chemical communications (Cambridge, England)

S Triki, F Thétiot, J S Pala, S Golhen, J M Clemente-Juan, C J Gómez-García, E Coronado

Affiliations

  1. UMR CNRS 6521, Univ. de Bretagne Occidentale, BP 809, 29285 Brest, France. [email protected]

PMID: 12240097 DOI: 10.1039/b105231b

Abstract

A new polynuclear copper(II) complex [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4Cl2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation.

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