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Chem Commun (Camb). 2001 Oct 07;(19):1966-7. doi: 10.1039/b106808c.

Palladium-catalysed cross-coupling reactions in supercritical carbon dioxide.

Chemical communications (Cambridge, England)

T R Early, R S Gordon, M A Carroll, A B Holmes, R E Shute, I F McConvey

Affiliations

  1. Melville Laboratory for Polymer Synthesis, Department of Chemistry, University of Cambridge, Pembroke Street, Cambridge, UK CB2 3RA.

PMID: 12240242 DOI: 10.1039/b106808c

Abstract

Heck and Suzuki reactions proceed in good yield in supercritical carbon dioxide in the presence of palladium acetate and tri-tert-butylphosphine with both free and polymer-tethered substrates.

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