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Chem Commun (Camb). 2002 Oct 21;(20):2342-3. doi: 10.1039/b205722k.

Spontaneous resolution and absolute configuration of a coordination polymer formed by MnII and a ferrocene-based bisnitronyl nitroxide radical.

Chemical communications (Cambridge, England)

Christian Sporer, Klaus Wurst, David B Amabilino, Daniel Ruiz-Molina, Holger Kopacka, Peter Jaitner, Jaume Veciana

Affiliations

  1. Institut für Allgemeine Anorganische und Theoretische Chemie, Universität Innsbruck, A-6020 Innrain 52a, Austria.

PMID: 12430431 DOI: 10.1039/b205722k

Abstract

Crystallisation of a ferrocenyl bis(nitronyl nitroxide) with manganese(II) bis(hexafluoroacetylacetonate) gives rise to spontaneous resolution of a coordination polymer formed by the two units creating seven sources of chirality.

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