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J Org Chem. 2003 Jan 24;68(2):452-9. doi: 10.1021/jo0205309.

P(i-BuNCH2CH2)3N: an effective ligand in the palladium-catalyzed amination of aryl bromides and iodides.

The Journal of organic chemistry

Sameer Urgaonkar, M Nagarajan, J G Verkade

Affiliations

  1. Department of Chemistry, Gilman Hall, Iowa State University, Ames 50011, USA.

PMID: 12530871 DOI: 10.1021/jo0205309

Abstract

It is shown that the bicyclic triaminophosphine P(i-BuNCH2CH2)3N serves as an effective ligand for the palladium-catalyzed amination of a wide array of aryl bromides and iodides. Other bicyclic or acyclic triaminophosphines, even those of similar basicity and/or bulk, were inferior.

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