Display options
Cite
Zhang QA, Nakamura Y, Oikawa KI, et al. New alkaline earth aluminum hydride with one-dimensional zigzag chains of [AlH6]: synthesis and crystal structure of BaAlH5. Inorg Chem. 2002;41(26):6941-3doi: 10.1021/ic020388u.
Zhang, Q. A., Nakamura, Y., Oikawa, K. I., Kamiyama, T., & Akiba, E. (2002). New alkaline earth aluminum hydride with one-dimensional zigzag chains of [AlH6]: synthesis and crystal structure of BaAlH5. Inorganic chemistry, 41(26), 6941-3. https://doi.org/10.1021/ic020388u
Zhang, Qing-An, et al. "New alkaline earth aluminum hydride with one-dimensional zigzag chains of [AlH6]: synthesis and crystal structure of BaAlH5." Inorganic chemistry vol. 41,26 (2002): 6941-3. doi: https://doi.org/10.1021/ic020388u
Zhang QA, Nakamura Y, Oikawa KI, Kamiyama T, Akiba E. New alkaline earth aluminum hydride with one-dimensional zigzag chains of [AlH6]: synthesis and crystal structure of BaAlH5. Inorg Chem. 2002 Dec 30;41(26):6941-3. doi: 10.1021/ic020388u. PMID: 12495328.
Copy Download .nbib Format: NLM
Share it on

Inorg Chem. 2002 Dec 30;41(26):6941-3. doi: 10.1021/ic020388u.

New alkaline earth aluminum hydride with one-dimensional zigzag chains of [AlH6]: synthesis and crystal structure of BaAlH5.

Inorganic chemistry

Qing-An Zhang, Yumiko Nakamura, Ken-ich Oikawa, Takashi Kamiyama, Etsuo Akiba

Affiliations

  1. National Institute of Advanced Industrial Science and Technology, AIST Tsukuba Central 5, 1-1-1 Higashi, Ibaraki 305-8565, Japan.

PMID: 12495328 DOI: 10.1021/ic020388u

Abstract

The title hydride and its deuteride were successfully synthesized. The crystal structure of the deuteride was determined by time-of-flight neutron powder diffraction. BaAlD(5) crystallizes with a new orthorhombic structure in space group Pna2(1) (No. 33), cell parameters a = 9.194(1) A, b = 7.0403(9) A, and c = 5.1061(6) A, Z = 4. BaAlH(5) is the first example that contains one-dimensional zigzag chains of [AlH(6)] along the crystallographic c axis.

Publication Types