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Richards AF, Phillips AD, Olmstead MM, et al. Isomeric forms of divalent heavier group 14 element hydrides: characterization of Ar'(H)GeGe(H)Ar' and Ar'(H)(2)GeGeAr'.PMe(3) (Ar' = C(6)H(3)-2,6-Dipp(2); Dipp = C(6)H(3)-2,6-Pr(i)(2)). J Am Chem Soc. 2003;125(11):3204-5doi: 10.1021/ja029772g.
Richards, A. F., Phillips, A. D., Olmstead, M. M., & Power, P. P. (2003). Isomeric forms of divalent heavier group 14 element hydrides: characterization of Ar'(H)GeGe(H)Ar' and Ar'(H)(2)GeGeAr'.PMe(3) (Ar' = C(6)H(3)-2,6-Dipp(2); Dipp = C(6)H(3)-2,6-Pr(i)(2)). Journal of the American Chemical Society, 125(11), 3204-5. https://doi.org/10.1021/ja029772g
Richards, Anne F, et al. "Isomeric forms of divalent heavier group 14 element hydrides: characterization of Ar'(H)GeGe(H)Ar' and Ar'(H)(2)GeGeAr'.PMe(3) (Ar' = C(6)H(3)-2,6-Dipp(2); Dipp = C(6)H(3)-2,6-Pr(i)(2))." Journal of the American Chemical Society vol. 125,11 (2003): 3204-5. doi: https://doi.org/10.1021/ja029772g
Richards AF, Phillips AD, Olmstead MM, Power PP. Isomeric forms of divalent heavier group 14 element hydrides: characterization of Ar'(H)GeGe(H)Ar' and Ar'(H)(2)GeGeAr'.PMe(3) (Ar' = C(6)H(3)-2,6-Dipp(2); Dipp = C(6)H(3)-2,6-Pr(i)(2)). J Am Chem Soc. 2003 Mar 19;125(11):3204-5. doi: 10.1021/ja029772g. PMID: 12630862.
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J Am Chem Soc. 2003 Mar 19;125(11):3204-5. doi: 10.1021/ja029772g.

Isomeric forms of divalent heavier group 14 element hydrides: characterization of Ar'(H)GeGe(H)Ar' and Ar'(H)(2)GeGeAr'.PMe(3) (Ar' = C(6)H(3)-2,6-Dipp(2); Dipp = C(6)H(3)-2,6-Pr(i)(2)).

Journal of the American Chemical Society

Anne F Richards, Andrew D Phillips, Marilyn M Olmstead, Philip P Power

Affiliations

  1. Department of Chemistry, University of California-Davis, One Shields Avenue, Davis, CA 95616, USA.

PMID: 12630862 DOI: 10.1021/ja029772g

Abstract

The reduction of Ar'GeCl (Ar' = C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2) with LiBH(Bus)3 affords the first heavier group 14 element dimetallene hydride Ar'(H)GeGe(H)Ar' which, upon further reaction with PMe3, yields the base-stabilized isomeric form Ar'(H)2GeGeAr'.PMe3.

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