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Ahmad R, Dix I, Hardie MJ. Hydrogen-bonded superstructures of a small host molecule and lanthanide aquo ions. Inorg Chem. 2003;42(7):2182-4doi: 10.1021/ic026071b.
Ahmad, R., Dix, I., & Hardie, M. J. (2003). Hydrogen-bonded superstructures of a small host molecule and lanthanide aquo ions. Inorganic chemistry, 42(7), 2182-4. https://doi.org/10.1021/ic026071b
Ahmad, Ruksanna, et al. "Hydrogen-bonded superstructures of a small host molecule and lanthanide aquo ions." Inorganic chemistry vol. 42,7 (2003): 2182-4. doi: https://doi.org/10.1021/ic026071b
Ahmad R, Dix I, Hardie MJ. Hydrogen-bonded superstructures of a small host molecule and lanthanide aquo ions. Inorg Chem. 2003 Apr 07;42(7):2182-4. doi: 10.1021/ic026071b. PMID: 12665345.
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Inorg Chem. 2003 Apr 07;42(7):2182-4. doi: 10.1021/ic026071b.

Hydrogen-bonded superstructures of a small host molecule and lanthanide aquo ions.

Inorganic chemistry

Ruksanna Ahmad, Ina Dix, Michaele J Hardie

Affiliations

  1. Department of Chemistry, University of Leeds, Leeds LS2 9JT, U.K.

PMID: 12665345 DOI: 10.1021/ic026071b

Abstract

Despite containing only relatively small molecular components, the structure of [Eu(H(2)O)(9)](1.5)(CTV)(6)(CH(3)CN)(5.5)(H(2)O)(7.5)[Co(C(2)B(9)H(11))(2)](4.5) (C(191)H(337.5)B(81)Co(4.5)Eu(1.5)N(5.5)O(57), a = 54.590(2) A, b = 37.5788(17) A, c = 31.8067(14) A, beta = 116.573(2) degrees, monoclinic, C2/c, Z = 8) is of an unusually large size and level of complexity, with an intricate hydrogen-bonding network formed between lanthanide aquo ions, water, and the small host molecule cyclotriveratrylene (=CTV). The 3D hydrogen-bonded network structure that results is unique and too complicated to apply the usual topological analysis. Instead a simplified model using structural subunits is described.

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