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Dambacher J, Bergdahl M. Employing the simple monosilylcopper reagent, Li[PhMe2SiCuI], in 1,4-addition reactions. Chem Commun (Camb). 2003;(1):144-5doi: 10.1039/b210792a.
Dambacher, J., & Bergdahl, M. (2003). Employing the simple monosilylcopper reagent, Li[PhMe2SiCuI], in 1,4-addition reactions. Chemical communications (Cambridge, England), (1), 144-5. https://doi.org/10.1039/b210792a
Dambacher, Jesse, and Bergdahl, Mikael. "Employing the simple monosilylcopper reagent, Li[PhMe2SiCuI], in 1,4-addition reactions." Chemical communications (Cambridge, England) vol. ,1 (2003): 144-5. doi: https://doi.org/10.1039/b210792a
Dambacher J, Bergdahl M. Employing the simple monosilylcopper reagent, Li[PhMe2SiCuI], in 1,4-addition reactions. Chem Commun (Camb). 2003 Jan 07;(1):144-5. doi: 10.1039/b210792a. PMID: 12611007.
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Chem Commun (Camb). 2003 Jan 07;(1):144-5. doi: 10.1039/b210792a.

Employing the simple monosilylcopper reagent, Li[PhMe2SiCuI], in 1,4-addition reactions.

Chemical communications (Cambridge, England)

Jesse Dambacher, Mikael Bergdahl

Affiliations

  1. Department of Chemistry, San Diego State University, San Diego, CA 92182-1030, USA.

PMID: 12611007 DOI: 10.1039/b210792a

Abstract

Conjugate addition reactions using the simple Li[PhMe2SiCuI] reagent to a variety of alpha,beta-unsaturated carbonyl compounds is described; dimethyl sulfide from the purification of CuI plays a key role for very high yields as well as high stereoselectivities in the formation of beta-silyl carbonyl compounds.

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