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Chem Commun (Camb). 2003 Jan 07;(1):158-9. doi: 10.1039/b210146g.

Light induced excited high spin-state trapping in [FeL2](BF4)2 (L = 2,6-di(pyrazol-1-yl)pyridine).

Chemical communications (Cambridge, England)

Victoria A Money, Ivana Radosavljevic Evans, Malcolm A Halcrow, Andrés E Goeta, Judith A K Howard

Affiliations

  1. Chemistry Department, Durham University, South Road, Durham, UK DH1 3LE.

PMID: 12611014 DOI: 10.1039/b210146g

Abstract

The spin-crossover complex [FeL2](BF4)2 undergoes a LIESST transition at 30 K on irradiation; the structures of the low-spin ground and high-spin metastable states at this temperature are presented.

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