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Petrella AJ, Roberts NK, Craig DC, et al. Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene. Chem Commun (Camb). 2003;(8):1014-5doi: 10.1039/b301075a.
Petrella, A. J., Roberts, N. K., Craig, D. C., Raston, C. L., & Lamb, R. N. (2003). Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene. Chemical communications (Cambridge, England), (8), 1014-5. https://doi.org/10.1039/b301075a
Petrella, Antonella J, et al. "Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene." Chemical communications (Cambridge, England) vol. ,8 (2003): 1014-5. doi: https://doi.org/10.1039/b301075a
Petrella AJ, Roberts NK, Craig DC, Raston CL, Lamb RN. Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene. Chem Commun (Camb). 2003 Apr 21;(8):1014-5. doi: 10.1039/b301075a. PMID: 12744346.
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Chem Commun (Camb). 2003 Apr 21;(8):1014-5. doi: 10.1039/b301075a.

Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(IV) complexes of p-tBu-calix[6]arene.

Chemical communications (Cambridge, England)

Antonella J Petrella, Nicholas K Roberts, Donald C Craig, Colin L Raston, Robert N Lamb

Affiliations

  1. School of Chemical Sciences, University of New South Wales, Sydney, Australia.

PMID: 12744346 DOI: 10.1039/b301075a

Abstract

Reaction of p-'Bu-calix[6]arene with potassium metal in methanol followed by [TiCp2Cl2] affords novel mononuclear and binuclear monocyclopentadienyl titanium(IV) complexes, both having the same inverted double cone conformation with a Cp in one of the cavities, in both complexes.

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